Gorbaciov Mihail

Title/degree Doctor, assoc. prof. 
Position Senior scientific researcher
Laboratory Physical and Quantum Chemistry
Office 447
Phone/fax (+373 22) 73 96 75
Email [email protected]
[email protected]
Professional links ORCID
Google Scholar
Scopus Author ID
Researchgate
Instrumentul Bibliometric Național
AGEPI: D-9M63001 (Institute for Scientific Information: Denmark)
Research areas

Physical chemistry: quantum chemistry, physical chemistry of liquids, investigation of quantitative structure – activity relationships (QSAR)

Relevant publications
Projects
  1. GORINCHOY, N.; BALAN, I.; GORBACHEV, M.; ARSENE, I.; POLINGER, V.; DUCA, Gh.; BERSUKER, I. The h-bond in environmental redox processes as a Pseudo-Jahн-Teller Effect. The 7th International Conference: "Ecological and Environmental Chemistry-2022", March 3-4, 2022, Chisinau, Republic of Moldova, EEC-2022 Abstract Book, Volume 1, p. 30. DOI: http://dx.doi.org/10.19261/eec.2022.v1,  http://eec-2022.mrda.md/wp-content/uploads/2016/02/EEC-2022-Abstract-Book-Vol-1-Final.pdf
  2. GORBACHEV, M.; GORINCHOY, N.; BALAN, I. Ionic quasi-splet mechanism of the interaction of some organic antioxidant acids with the radicals ABTS•+ and DPPH•. The 7th International Conference: "Ecological and Environmental Chemistry-2022", March 3-4, 2022, Chisinau, Republic of Moldova, EEC-2022 Abstract Book, Volume 1, p. 50. DOI: http://dx.doi.org/10.19261/eec.2022.v1http://eec-2022.mrda.md/wp-content/uploads/2016/02/EEC-2022-Abstract-Book-Vol-1-Final.pdf
  3. GORBACHEV, M.; GORINCHOY, N. Molecular Orbital Nature of the Atmospheric Reactions Between the NO3• radical and C3 – C10 n-Alkanes: DFT Study. The 7th International Conference: "Ecological and Environmental Chemistry - 2022",  Chisinau, Republic of Moldova, Book of Abstracts EEC-2022, p. 44.
  4. ARSENE, I.; GORINCHOY, N.; GORBACHEV, M. Theoretical Study of the Three-Stages Radical Mechanism of the Reaction of Dihydroxyfumaric Acid with the Stable Radical DPPH•. The 7th International Conference: "Ecological and Environmental Chemistry - 2022",  Chisinau, Republic of Moldova, p. 41.
  5. GORBACHEV, M.; GORINCHOY, N.; BALAN, I. Some particularities of the reaction between antioxidant phenolic acids and the free radical ABTS•+: A comparative DFT study for the gas phase and ethanol. Chemistry Journal of Moldova, 2022, 17(1), DOI: http://dx.doi.org/10.19261/cjm.2021.919, http://www.cjm.asm.md/accepted_papers
  6. ARSENE, I.; GORINCHOY, N.; GORBACHEV, M. Theoretical study of the mechanism of the free radical DPPH• inhibition process under the action of vitamin C. Conferinţa ştiinţifico-practică internațională „Instruire prin cercetare pentru o societate prosperă” 19-20 martie 2022 Volumul II Chimie. Proceedings, p. 20-25. ISBN 978-9975-76-391-2
  7. GORBACHEV, M.; GORINCHOY, N.; BALAN, I.; ARSENE, I. DFT evidence of charge transfer complexes formation in reactions of organic antioxidant acids with the DPPH• and ABTS•+ radicals: the crucial role of solvents. Conferinţa ştiinţifico-practică internațională „Instruire prin cercetare pentru o societate prosperă” 19-20 martie 2022 Volumul II Chimie. Proceedings, p. 127-132. ISBN 978-9975-76-391-2.
  8. BALAN, I.; GORBACHEV, M.; GORINCHOY, N.; ARSENE, I. Pseudo jahn-teller origin of the proton-transfer energy barrier in the proton-bound dimers. Conferinţa ştiinţifico-practică internațională „Instruire prin cercetare pentru o societate prosperă”, 19-20 martie, 2022, Volumul II Chimie, Proceedings, p. 43-49. ISBN 978-9975-76-391-2.
  9. Gorbachev M.Yu.,Gorinchoy N.N., Osipov I. Accelerated decomposition of the fungicide, iprodione, on TiO2surface under solar irradiation: experimental study and DFT mechanisms. Journal of Environmental Science and Health. Part B, 2020, v.55, doi:10.1080/03601234.2020.1790965
  10. Osipov I., Gorbachev M.Yu., Gorinchoy N.N. Proton-induced accelerated decae of the fungicide, vinclozolin, on TiO2surface under solar irradiation: Experimental and DFT study. Journal of Environmental Science and Health. Part B, 2018, v.53, N4, pp. 222-228. doi.org/10.1080/03601234.2017.1410406
  11. M.Yu. Gorbachev, N.N. Gorinchoy, I. Arsene, Surface tension of near-boiling liquids with intramolecular πσ*-hyperconjugation: DFT calculations. Journal of Molecular Liquids, 2017, 237, pp. 108-112.
  12. Gorbachev M.Yu., Gorinchoy N.N., Arsene I., Antioxidant properties of dihydroxyfumaric acid and its dimethyl ether: a comparative DFT study of their reactions with the stable radical DPPH*. Chemistry Journal of Moldova, 2015 Volume 10, no.1, pp. 89-94. dx.doi.org/10.19261/cjm.2015.10(1).13
  13. Mikhail Yu. Gorbachev, Olga Budei, Ion Arsene, Natalia N. Gorinchoy, Surface tension of liquids with π-conjugated planar molecules: DFT calculation, Journal of Molecular Liquids, 2014, 190,pp. 50–53.
  14. Gorbachev M.Yu., Gorinchoy N.N., Balan I.Quantitative relationship between antioxidant activity of 4-hydroxycinnamic acid derivatives and particularities of their electronic structure: DFT study. In the Abstract Book: “III International (XIII Ukrainian) Scientific Conference “Current Chemical Problems”, 2020,Vinnytsia, Ukraine, p. 31.
  15. Arsene I., Gorbachev M.Yu., Gorinchoy N.N. DFT Study of Radical Mechanism for the Reaction of Dihydroxifumaric Acid with the Stable Radical DPPH*, In the Abstract Book: “III International (XIII Ukrainian) Scientific Conference “Current Chemical Problems”, 2020, Vinnytsia, Ukraine, p. 30.
  16. Gorbachev M.,Gorinchoy N. DFT study of photo-transformation of cyprodinil caused by change of its tautomeric form under sunlight action. In the Book of Abstract: “Achievements and perspectives of modern chemistry”, 2019, Chisinau, Republic of Moldova, P38.
  17. Gorbachev M., Arsene I., Gorinchoy N. Influence of nano-particles of TiO2 on relative antioxidant activities of fumaric and dihydroxyfumaric acids: DFT investigation of their reactions with DPPH. In the Book of Abstract: “Achievements and perspectives of modern chemistry”, 2019, Chisinau, Republic of Moldova, P39.
  18. Gorbachev M.,Gorinchoy N.Ionic liquids: simple ‘structure – critical temperature’ relationship. In the Book of Abstract: “Achievements and perspectives of modern chemistry”, 2019, Chisinau, Republic of Moldova, P40.
  19. Gorbachev M.,Gorinchoy N., Osipov I. DFT evidence of proton-induced decay of the fungicide, iprodione, on TiO2 surface under solar irradiation. In the Book of Abstract: “Achievements and perspectives of modern chemistry”, 2019, Chisinau, Republic of Moldova, P41.  

National projects

  1. ANCD/20.80009.5007.27. Physico-chemical mechanisms of redox processes with electron transfer involved in vital, technological and environmental systems
    Period: 2020-2023
    Project manager: Acad., dr. habilitate, prof. Gheorghe DUCA
  2. CSSDT/15.817.02.02F. Study of mechanisms of chemical reactions, electronic structure and physico-chemical properties of transitiom-metal coordination compounds and nanoparticles A2B6
    Period: 2015-2019
    Project manager: Dr., assoc. prof. Natalia GORINCIOI