Laboratory Physical and Quantum Chemistry

lab
Head of the laboratory dr.
 Iolanta BALAN
  

Office:  432a
Phone: (+373 22) 73 96 49
Email: [email protected]; [email protected]

  

 


Short history                                                 

The Laboratory of Quantum Chemistry was founded in 1964 at the initiative of acad. Isaac Bersuker, the world-renowned scientist who directed this scientific group for 29 years (1964-1993). 

In 1978 acad. Isaac Bersuker has discovered the „Phenomenon of tunneling splitting of the energy levels of polyatomic systems in degenerate electronic states”. The discovery has been registered in 1978 with No 202 in the State Register of the USSR, being one of the two scientific discoveries ever realized in Republic of Moldova.

In 2006, the laboratory was renamed in the Laboratory of Quantum Chemistry and Chemical Kinetics and later, in 2013, the laboratory was enlarged by the integration of the Laboratory of Magnetic Resonance and Laser Spectroscopy headed by corresponding member Ion Geru, hence the name of the laboratory was replaced by the Laboratory of Quantum Chemistry, Chemical Kinetics and Magnetic Resonance. In 2016 the name of the laboratory became Quantum Chemistry, Catalysis and Physical Methods. Since 2020 laboratory is renamed in Physical and Quantum Chemistry.

 

Research areas
  • Quantum chemical calculations of geometry, electronic structure and properties of molecular sistems by ab initio and DFT method;
  • Development of the theory of vibronic interactions. Pseudo Jahn-Teller Effect (PJTE) in control and rationalization of chemical transformations. Vibronic activation of small molecules by coordination;
  • Theoretical and experimental studies of the mechanisms of chemical reactions. Study of the „structure-activity” and „structure-properties” relationships;
  • Synthesis of colloidal quantum dots II-VI and  study of their properties by methods of optical spectroscopy and magnetic resonance. Processes of self-organization of II-VI colloidal quantum dots in organic solvents;
  • Theoretical interpretation of anomalous magnetic properties of trihomonuclear clusters with Kramers’ degeneration of energy levels based on the time- reversal symmetry;
  • Application of the time-reversal symmetry for developing of synthesis methods for binuclear coordination compounds with controlled magnetic properties;
  • Production of nano-structured catalysts based on TiO2 and doping of their surface with noble metals with the chemical-catalytic methods in order to enlarge their applications in photocatalytic systems, specifically, for the persistent organic pollutants decomposition in water compartments;
  • Spectroscopy and molecular dynamics simulations of the conformation of biological macromolecules.
Staff
Recent publications
Research projects

 Iolanta BALAN
 dr.                                                           Head of the laboratory

office 432a
phone: (+373 22) 73 96 49

email: [email protected]; iolan[email protected]

Gheorghe DUCA
dr. habilitate, prof., academician ASM
Principal scientific researcher

office 225
phone: (+373 22) 72 79 11
email: [email protected]; [email protected]
www: duca.md

Isaac BERSUKER
dr. habilitate, prof., academician ASM
Consultant

office 446
phone: (+373 22) 73 96 49
email: [email protected]

Ion GERU
dr. habilitate, prof., corr. memb. ASM
Principal scientific researcher

office 244,
phone: (+373 22) 73 54 17
email: [email protected]; [email protected]
 

Olga COVALIOVA
dr. habilitate
Leading scientific researcher

office 225
phone: (+373 22) 72 79 11
email: [email protected];  [email protected]

Natalia GORINCIOI
dr., assoc. prof.
Leading scientific researcher

office 446
phone: (+373 22) 73 96 49
email: [email protected]; [email protected] 

Mihail GORBACIOV
dr.
Senior scientific researcher
office 447
phone: (+373 22) 73 96 49
email: [email protected]; [email protected]
 

Lilia ANGHEL
dr.
Senior scientific researcher

office 220
phone: (+373 22) 73 96 49

email: [email protected]; [email protected]

Alic BARBA
dr.
Leading scientific researcher

office 145
phone: (+373 22) 73 96 49
email: [email protected];  [email protected]

Lidia ROMANCIUC
dr.
Senior scientific researcher

office 225
phone: (+373 22) 72 79 11
email: [email protected] ; [email protected]

Elena GORINCIOI
dr., assoc. prof.
Senior scientific researcher

office 145
phone: (+373 22) 73 96 49
email: [email protected] ; [email protected]

Ion ARSENE
dr.
Senior scientific researcher

office 449
phone: (+373 22) 73 96 49
email: [email protected] ; [email protected]

Olga IALTICENCO
dr.

Senior scientific researcher

birou 449
tel.: (+373 22) 73 96 49
email: [email protected]

Crina VICOL
Scientific researcher
PhD student

office 219
phone: (+373 22) 73 96 49
email: [email protected]; [email protected]

Constantin HRAMCO
Scientific researcher
PhD student

office 219
phone: (+373 22) 73 96 49
email: [email protected]

Monographs

  1. DUCA, Gh.; VASEASHTA, A. Handbook of Research ”Emerging Developments and Environmental Impacts of Ecological Chemistry”. IGI Global, SUA., 2020. 649 p. ISBN13: 9781799812418, ISBN10: 1799812413, EISBN13: 9781799812432, doi:10.4018/978-1-7998-1241-8.
  2. DUCA, Gheorghe. Contribuţii la societatea bazată pe cunoaştere. Editura Mutarcim (Turcia), 2019, 302 p. ISBN 978-9952-4713-6-6.
  3. XU, Jiuping; EJAZ Ahmed Syed Cooke, FANG Lee; DUCA Gheorghe. Proceeding of the Thirteenth International Conference on Management Science and Engineering Management, Springer, 2019, Springer, 2019, vol II, 782 p. ISBN: 978-3-030-21254-4, ISBN: 978-3-030- 21255-1 (eBook).
  4. XU, Jiuping; EJAZ Ahmed, Syed; Cooke, FANG Lee, DUCA Gheorghe. Proceeding of the Thirteenth International Conference on Management Science and Engineering Management. Springer, 2019, vol I. ISBN: 978-3-030-21247-6, ISBN: 978-3-030-21248-3 (eBook).
  5. GERU, I.I. Time-Reversal Symmetry. Seven Time-Reversal Operators for Spin Containing Systems. Springer Tracts in Modern Physiscs, Vol. 281, Springer Nature Switzerland, AG, 2018, 362 p.
  6. КОВАЛЕВ, B.; ДУКА, Г.; КОВАЛЕВА, О. «Зеленая энергия»: инновационные экобиотехнологии и комбинированные реакторы. Антология изобретений. Ин-т химии Акад. Hаук Молдовы, Научн.-исслед. Центр Прикладной и экологической химии Молдавского госуниверситета, Кишинэу: CEP USM, 2017, 504 c., ISBN 978-9975-71-902-5.
     

Chapters in monographs (national / international):

  1. GORINCIOI, N.N.; BERSUKER, I.B. Origin of puckering (buckling) of planar heterocycles and methods of its suppression. In: Heterocycles, Danielsen J.M.(ed.), Nova Science Publishers, Inc., 2020, p. 129-188. ISBN: 978-1-53617-804-3 
  2. VASEASHTA, A.; DUCA, Gh,; CULIGHIN, E.; BOGDEVICI, O.; KHUDAVERDYAN, S. Smart and Connected Sensors Network for Water Contamination Monitoring and Situational Awareness. In book: Functional Nanostructures and Sensors for CBRN Defence and Environmental Safety and Security (NATO Science for Peace and Security Series C: Environmental Security), January 2020, pp 283-296. doi: http://doi.org/10.1007/978-94-024-1909-2_19.
  3. POVAR, I.; SPINU, O.; LUPASCU, T.; DUCA, Gh. Thermodynamic Stability of Natural Aqueous Systems. In: Handbook of Research ”Emerging Developments and Environmental Impacts of Ecological Chemistry”. IGI Global, SUA., 2020 pp 76-108, doi: 10.4018/978-1-7998-1241-8.ch004.
  4. DUCA, Gh.; MEREUTA, A.; TĂNĂSELIA, C.; LEVEI, E.; VELISCO, N. Assessment of Surface Water Pollution With Heavy Metals. In: Handbook of Research ”Emerging Developments and Environmental Impacts of Ecological Chemistry”. IGI Global, SUA., 2020, pp 212-228, doi: 10.4018/978-1-7998-1241-8.ch010.
  5. DUCA, Gh.; COVALIOV, V.; COVALIOVA, O. Intensive Biochemical Processes of Wastewater Treatment With High Caloricity Biogas Production. In: Handbook of Research ”Emerging Developments and Environmental Impacts of Ecological Chemistry”. IGI Global, SUA., 2020, pp 291-306, doi: 10.4018/978-1-7998-1241-8.ch013.
  6. GLADCHI V., BUNDUCHI E., ROMANCIUC L. Ecological Chemistry of Natural Waters. In: ”Emerging Developments and Environmental Impacts of Ecological Chemistry” de către Editura IGI Global, SUA, Co-editor Acad. Gh.Duca. https://www.igi-global.com/book/handbook-research-emerging-developments-environmental/231905., pp.197-211.
     

Articles in international Journals (SCOPUS and with IF)

  1. DUCA, Gh.; TRAVIN, S.O. Reactions’ Mechanisms and Applications of Hydrogen Peroxide. American Journal of Physical Chemistry. 2020, 9(2). ISSN: 2327-2430 (Print); ISSN: 2327-2449 (Online). pp. 36-44. doi:10.11648/j.ajpc.20200902.13
  2. DUCA, Gh.; COVALIOV, V.; COVALIOVA, O. Production, Structure and Photocatalytic Properties of Nanotubular TiO2. Environmental Engineering and Management Journal. 2020, 19(1), p. 1-10. – ISSN: 582-9596
  3. ANGHEL, L.; DUCA, Gh.; CEPOI , L.; IATCO, I.; RUDI, L.; ERHAN, R.V. The Effects of Operational Parameters on the Iron(III) Uptake by Micro-Algae Dunaliella salina. Clean – Soil, Air, Water, 2018, 1800157, 7 p. doi: 10.1002/clen.201800157 (IF:1.412)
  4. ANGEL, L.; RADULESCU, A.; ERHAN, R. V. Structural aspects of human lactoferrin in the iron binding process studied by molecular dynamics and small-angle neutron scattering. European Journal of Physics E – Soft Matter & Biological Physics, 2018, 41:109, 7 p. DOI: 10.1140/epje/i2018-11720-x, (IF 1.802).
  5. ARICU, A.; CIOCARLAN, L.; LUNGU, A.; BARBA, A.; SHOVA, S.; ZBANCIOC, G.; D’AMBROSIO, M.D.; VORNICU, N. Synthesis, antibacterial, and antifungal activities of new drimane sesquiterpenoids with azaheterocyclic units. Med. Chem. Res., 2016, 25(10),  (IF 1.436)
  6. CEPOI, L.; RUDI, L.; CHIRIAC, T.; VALUTA, A.; ZINICOVSCAIA, I.; DUCA, GH.; KIRKESALI, E.; FRONTASIEVA, M.V.; CULICOV, O.; PAVLOV, S.S.; BOBRIKOV, I. Biochemical changes in some cultures of cyanobacteria at the synthesis of silver nanoparticles. Canadian Journal of Microbiology. 2015, 61(1), p. 13-21, doi: 10.1139/cjm-2014-0450 (IF: 1.241).
  7. CIOCARLAN, A.;  ARICU, A.; LUNGU, L.; EDU, C.; BARBA, A.; SHOVA, S.;  MANGALAGIU, I.; D’AMBROSIO, M.; NICOLESCU, A.; DELEANU, C.; VORNICU, N. New Synthetic Applications of Methyl 7-Oxo-13,14,15,16-tetranorlabd-8-en-12-oate of Potential Practical Interest. Synlett, 2017, 28(05), p. 565-571, (IF: 2,151).
  8. GERU I.I. Molecular photoeffect in singe- and multi-wall carbon nanotubes with physisorbed oxigen molecules. Physics Letters A, 2017, 381 (48), p. 4019-4022, (IF: 1,772).
  9. GORBACHEV, M.Yu.; GORINCHOY, N.N.; ARSENE, I. Surface tension of near-boiling liquids with intramolecular πσ*-hyperconjugation: DFT calculations. Journal of Molecular Liquids, 2017, 237, p. 108–112, (IF: 2,68).
  10. GRINCO, M.; GÎRBU, V.; GORINCIOI, E.; BARBA, A.; KULCITKI, V.; UNGUR, N. The first biomimetic synthesis of a diterpenoid with the ent-verrucosin A/B skeleton. Tetrahedron Letters, 2016, 57(19), p. 2084– 2086, (IF: 2.379).
  11. ILKHANI, A.; GORINCHOY, N.; BERSUKER, I.B. Pseudo Jahn–Teller effect in distortion and restoration of planar configurations of tetra-heterocyclic 1,2-diazetes C2N2E4, E = H, F, Cl, Br. Chemical Physics, 2015, 460, p. 106–110, (IF: 1,696).
  12. ILKHANI, A.; HERMOSO, W.; BERSUKER, I.B. Pseudo Jahn-Teller origin of instability of planar configurations of hexa-heterocycles. Application to compounds with 1,2- and ,4-C4X2 skeletons (X = O, S, Se, Te). Chemical Physics, 2015, 460, p. 75–82, (IF: 1,696).
  13. MARIN, I.; Turta, C.; BENNISTON, A.C.; HARRINGTON, R.W.; CLEGG, W. Homoleptic and Heteroleptic Ruthenium(II) Complexes Based on 2,6-Bis(quinolin-2-yl)pyridine Ligands – Multiple-Charged-State Modules for Potential Density Memory Storage. European Journal of Inorganic Chemistry. 2015, 5, p. 786–793, (IF: 2.965).
  14. OSIPOV, I.; GORBACHEV, M.Y.; GORINCHOY, N.N. Proton-induced accelerated decay of the fungicide, vinclozolin, on TiO2 surface under solar irradiation: Experimental and DFT study. Journal of Environmental Science and Health, 2018, Part B, 53:4, p. 222-228, DOI: 10.1080/03601234.2017.1410406. (IF: 1.31).
  15. ZINICOVSCAIA, I.; CEPOI, L.; CHIRIAC, T.; RUDI, L.; CULICOV, O.A.; FRONTASIEVA, M.V.; PAVLOV, S.; KIRKESALI, E.; GUDORINA, S.; MITINA, T.; AKSHINTSEV, A.; RODLOVSKAYA, E. Spirulina platensis as biosorbent of chromium and nickel from wastewaters. Desalination and Water Treatment. 2015, doi: 10.1080/19443994.2015.1042061, (IF: 1.173).
  16. КАНАРОВСКИЙ, Е.Ю.; ЯЛТЫЧЕНКО, О.В.; ГОРИНЧОЙ, Н.Н. Кинетика антиоксидантной активности -токоферола и некоторых его гомологов. Часть 1. Обзор проблемы. Теоретическая модель. Электроная обработка материалов, 2017, 53(5), с. 48-66.
  17. ANGHEL, L.; ROGACHEV A.; KUKLIN A.; ERHAN, R.V. β-Lactoglobulin associative interactions: a small angle scattering study. European Biophysics Journal, 2019, 48(3), pp. 285-295 (IF 1.935) . https://doi.org/10.1007/s00249-019-01360-9
  18. LUNGU, L.; CIOCARLAN, A.; BARBA, A.; SHOVA, S.;  POGREBNOI, S.; MANGALAGIU, I.; MOLDOVEANU, C.; VORNICU, N.; D'AMBROSIO, M.;  BABAK, M.; ARION, V.; ARICU, A. Synthesis and evaluation of biological activity of homodrimane sesquiterpenoids bearing hydrazinecarbothioamide or 1,2,4-triazole unit. Chemistry of Heterocyclic Compounds 2019, 55(8), 716–724. ( https://doi.org/10.1007/s10593-019-02526-1) ISSN: 0009-3122  (IF 1.492).
  19. ARICU, A.N.; KUCHKOVA, K.I.; BARBA, A.N.; DRAGALIN, I.P.; SHOVA, S.G.; VORNICU, A.N.; GORINCIOI, E.K.; SECARA, E.S.; LUNGU, L.V.; NICULAUA, M.; UNGUR, N.D.; VLAD, P.F. Synthesis from norambreinolide, structure, and antimicrobial activity of dihomodrimane sesquiterpenoids with azine, hydrazide, and dihydrazide fragments. Chemistry of Natural Compounds, 2016, 52(6), p.1029-1036, (IF: 0.473).
  20. COROPCEANU, E.; BOLOGA, O.; ARSENE, I.; VITIU, A.; BULHAC, I.; GORINCHIOY, N.; BOUROSH, P. Synthesis and Characterization of Inner-Sphere Substitution Products in Azide-Containing Сobalt(III) Dioximates. Russian Journal of Coordination Chemistry, 2016, Vol. 42, No. 8, p. 516–538. ISSN: 1070-3284, (IF: 0.516).
  21. GORINCHOY, N.N. Pseudo Jahn-Teller Effect in Puckering and Planarization of Heterocyclic Compounds. International Journal of Organic Chemistry, 2018, 8, p. 142-159. https://doi.org/10.4236/ijoc.2018.81010, (IF: 0.32).
  22. GORINCHOY, N.N.; BERSUKER, I.B. Pseudo Jahn-Teller effect in control and rationalization of chemical transformations in two-dimensional compounds. Journal of Physics: Conf. Series, 2017, 833, 012010, doi:10.1088/1742-6596/833/1/012010, (IF: 0.45).
  23. GORINCHOY, N.N.; Arsene, I.; BERSUKER, I.B. Buckybowl structure of sumanenes and analogous compounds induced by the Pseudo Jahn-Teller Effect. Journal of Physics: Conf. Series, 2018, 1148, 012005, doi:10.1088/1742-6596/1148/1/012005, (IF: 0.45).
  24. KANAROVSKII, E.Yu.; Yaltychenko, O.V.; Gorinchoy, N.N. Kinetics of Antioxidant Activity of α-Tocopherol and Some of Its Homologues: Part 1. Review: Theoretical Model. Surface Engineering and Applied Electrochemistry, 2018, Vol. 54:5, p. 481–497. ISSN 1068-3755, (IF: 0.289).
  25. KUCHKOVA, K.; ARICU, A.; SECARA, E.; BARBA, A.; VLAD, P.; MACAEV, F.; MELNIC, E.; KRAVTOV, V. Synthesis and structure of homodrimane sesquiterpenoids containing 1,2,4-triazole and carbazole cycles. Chem. Nat. Compd. 2015, 54/4, p. 684-688, ISSN: 0009-3130, (IF: 0.509).
  26. КОРОПЧАНУ, Э.Б.; БОЛОГА, О.А.; АРСЕНЕ, И.; ВИТИУ, А.; БУЛХАК, И.И.; ГОРИНЧОИ, Н.Н.; БОУРОШ, П.Н. Синтез и исследование продуктов внутрисферного замещения в азид-содержащих диоксиматах Co(III). Координационная химия, 2016, 42, № 8, p. 480-502, (IF: 0.591)
     

Articles in other international journals

  1. GERU, I.I. Inversion of spin levels in exchange coupled pairs under combined time-reversal. Semiconductor Physics, Quantum Electronics and Optoelectronics, 21(3), 2018, p. 228-248
  2. АРЫКУ, А.Н.; КУЧКОВА, К.И.; СЕКАРА, Е.С.; БАРБА, А.Н.; ДРАГАЛИН, И.П.; МЕЛЬНИК, Е.; КРАВЦОВ, В.Х. Cинтез и структура дримановых сесквитерпеноидов, содержащих циклы пиримидина, пиразина, 1,2,4-триазола и карбазола. Химия Природных Соединений, 2018, Nr. 3, p. 386-390.
  3. КУЧКОВА, К.И.; АРЫКУ, А.Н.; СЕКАРА, Е.C.; БАРБА, А.Н.; ВЛАД, П.Ф.;  МАКАЕВ, Ф.З.; МЕЛЪНИК, Е.; КРАВЦОВ, В.Х.  Синтез и структура гомодримановых сесквитерпеноидов, содержащих циклы 1,2,4-триазола и карбазола. Хим. Природных Соединений, 2015, № 5, p.589 – 593.
  4. КОВАЛЕВ, В., КОВАЛЕВА, О., УНГУРЯНУ, Д. Изучение условий получения высококалорийного биогаза при повышенном давлении. Bulletin of Vologda State University. Science Journal, Vologda, RF, 2019, 3(5), pp. 46-52. ISSN 2658-3399.
     

Articles in national journals

  1. ANGHEL, L. An investigation of the protonation states of human lactoferrin iron-binding protein. Chemistry Journal of Moldova, 2015, 10(1), p. 70-74, ISSN: 1857-1727.
  2. ANGHEL, L.; ERHAN, R.V. Structural Aspects of Lactoferrin and Serum Transferrin Observed by FTIR Spectroscopy. Chemistry Journal of Moldova, 2018, 13(1), p. 111-116, doi: http://dx.doi.org/10.19261/cjm.2018.482, ISSN: 1857-1727.
  3. CUBA, L.; BOUROSH, P.; KRAVTSOV, V.; GORINCIOI, E.; DRAGANCEA, D. Oxido- and dioxidovanadium(V) complexes with o-vanillin semicarbazone: synthesis and crystal structure. Chemistry Journal of Moldova, 2018, 13(1), p. 36-45. DOI: http://dx.doi.org/10.19261/cjm.2018.477
  4. DUCA, Gh.; ARICU, A.; LUNGU, L.; TENU, N.; CIOCARLAN, A.; GUTU, Y.; DRAGALIN, I.; BARBA, A. Synthesis of new homodrimane sesquiterpenoids containing diazine, 1,2,4-triazole and carbazole rings. Chemistry Journal of Moldova, 2018, 13(1), p. 69-73. DOI: http://dx.doi.org/10.19261/cjm.2017.458.
  5. GORBACHEV, M; GORINCHOY, N.; ARSENE, I. Antioxidant properties of dihydroxyfumaric acid and its dimethyl ether: a comparative DFT study of their reactions with the stable radical DPPH*. Chemistry Journal of Moldova, 2015, 10(1), p. 89-94. ISSN: 1857-1727.
  6. GORINCIOI, E.; COROPCEANU, E. NMR studies of some Zn and Cd coordination compounds bearing 1,2-ciclohexanedionedioxime. Chemistry Journal of Moldova, 2018, 13(2), p. 38-47 DOI: http://dx.doi.org/10.19261/cjm.2018.368, ISSN: 1857-1727.
  7. GORINCHOY, N. Electronic control of molecular configuration instability via vibronic coupling. Pseudo Jahn-Teller stabilization of verticallz excited states of F2CO, N2H2 and H2C2O molecules. Chemistry Journal of Moldova, 2014, 9(2), p. 80-89. ISSN: 1857-1727.
  8. GORINCHOY, N. Structural distortions of coordinated ketene molecule induced by the Pseudo Jahn-Teller Effect. Chemistry Journal Of Moldova, 2016, 11(2), p. 99-104, http://dx.doi.org/10.19261/cjm.2016.11(2).09, ISSN: 1857-1727.  
  9. GUREV, A.; LUPASCU, G.; GORINCIOI, E. Iridoid glycosides from linaria genistifolia (L.) Mill. in biological control of soil-borne fungal pathogens of wheat and some structure considerations. Chemistry Journal of Moldova, 2015, 10(1), p. 57-63, ISSN: 1857-1727.
  10. OSIPOV, I. The surface photochemistry of procymidone in the presence of ammonium ferric citrate. Chemistry Journal of Moldova, 2015, 10(2), p. 89-91. ISSN: 1857-1727.
  11. ARSENE, I., GORINCHOY, N. DFT study of the entire reaction cycle of H2O2 decomposition and O2 generation catalyzed by Fenton reagent. Chemistry Journal of Moldova. 2019, 14(1), pp. 88-97. http://dx.doi.org/10.19261/cjm.2018.543.
  12. BALAN, I. Schimbările structurale în moleculele de tip AH3 în procesele redox induse de Pseudo Efectul Jahn-Teller. Studia Universitatis Moldaviae, 2017, nr.6(106), p. 86-92. http://studiamsu.eu/stiinte-ale-naturii/,
  13. GERU, I. Simetria reversării timpului şi rolul ei în sinteza controlată a compușilor coordinativi   binucleari.  Akademos, Revista de Ştiinţă, inovare, cultură şi artă, 2016, nr.2 (41), p. 45-50. ISSN 1857-0461.
  14. MARIN, I. Descompunerea fotocatalitică a apei ca sursă de energie regenerabilă. Akademos, Revista de Ştiinţă, inovare, cultură şi artă, 2017, nr. 3 (46), p. 56-59. ISSN 1857-0461.
  15. КОВАЛЕВ, В., КОВАЛЕВА, О., НЕННО, В. Разработка процессов очистки и кондиционирования биогаза. Studia Universitatis Moldaviae. Ser. Şt. reale şi ale naturii. 2019, 1(121), 141-148. ISSN 1814 3237. 
  16.  КОВАЛЕВ, В., КОВАЛЕВА, О., НЕННО, В. Повышение энергетических характеристик биогаза: Часть 1. Технологические факторы, влияющие на процесс метаногенеза. Intellectus. 2019, Nr.1-2, 143-151. ISSN 1857-0496.
     

Articls in abstract books

  1. CURLAT, S.; LOGHINA, L.; BARBA, A.; GORINCIOI, E.; MACAEV, F. Synthesis and stereochemistry of the 1,2-hydroxyl-amino derivatives of (1S,6R) -3,7,7- trimethylbicyclo[4.1.0]hept-3-ene. Proceedings of the XXI-st National Conference with International Participation „Progress in Cryogenics and Isotopes Separation”, 19-21 October 2016, Călimăneşti-Căciulata, Vâlcea, România, p. 73-74.
  2. DORIF, A.; GERU, I.; FRĂTESCU, V. Synthesis and characterization of ZnS colloidal quantum dots. Proceedings of the 5th Intern. Conf. on Telecommunications, Electronics and Informatics, May 20-23, Chişinău, 2015, p. 195-196.
  3. DUCA, Gh.; COVALIOVA, O. Intensified Water Treatment Methods. ICMSEM – International Conference on Management Science and Engineering Management, Baku, Azerbaijan, August, 2016, p. 86-97. Accession number: 20163602781367; DOI:  10. 1007/978-981-10-1837-4_86.
  4. GERU, I.I. Encoding the information in a quantum computing using effective spin two-boson representation. Proceedings of the 6-th International Conference “Telecommunications, Electronics and Informatics” ICTEI-2018, Chisinau, May 24-27, 2018, p.199-201.
  5. GERU, I.I. Time-Reversal Symmetry, Boson-Boson and Boson-Antiboson Correlations in Spin Systems. Progrese în Fizică Teoretică (coordonatori V.Canţer, F.Paladi, D.Nica), CEP USM, Chişinău, 2016, p. 22-95.
  6. GERU, I.I.; VOLODINA, G.F.; TIRON, S.D. On a possible self-organizationin a system of ZnO colloidal quantum dots. Proceedings of the 9th International Conference on Microelectronics and Computer Science, Chisinau, Moldova, October 19-21, 2017, p. 73-75.
  7. KANAROVSKII, E.Yu.; YALTYCHENKO, O.V.; GORINCHOY, N.N. Peroxidation kinetics involving  the complexes of cytochrome c  and cardiolipin in the presence of lipid antioxidants. Proceedings of the 9th International conference of Microelectronics and Computer Science. Chisinau, Moldova, October 19-21, 2017, p. 350-353.
  8. КОВАЛЕВА, О.В. Фотокаталитическая очистка природных и техногенных сточных вод. Материалы Международной конференции «Интегрированное управление бассейном трансграничного Днестра: платформа для сотрудничества и современные вызовы», Тирасполь,  26-27 октября 2017 г., p. 176-180.
  9. КОВАЛЕВА, О. Фотокаталитическое обезвреживание труднодеградируемых органических загрязнителей в водных системах. Мат. научно-практ. конф. «Биоразнообразие и факторы, влияюшие на экосистемы бассейна Днестра», Тирасполь,16-17 ноября, 2018, Ed. Print-Caro, ISBN 978 9975 56 578 3, p. 115-119.
  10. ЯЛТЫЧЕНКО, О.В.; КАНАРОВСКИЙ, Е.Ю.; ГОРИНЧОЙ, Н.Н.  Исследование Динамики Электронной Локализации в тетрамерном Металл-углеродном Нанокластере с Учетом Эффектов Поляризации. Proceedings of the 6-th International Conference  “Telecommunications Electronic and Informatics”  ICTEI-2018, Сhisinau, May 24-28, 2018,  p. 215-216
  11. KANAROVSKII, E.Y., YALTYCHEKO, O.V., GORINCHOY, N.N. Theoretical Model of Lipid Peroxidation Kinetics for Complexes of Cytochrome c and Cardiolipin with Participation of Antioxidants. In: Tiginyanu I., Sontea V., Railean S. (eds), Proceedings of the 4th International Conference on Nanotechnologies and Biomedical Engineering (ICNBME-2019),, vol 77. Springer, Cham, September 18-21, 2019, pp. 561–565. DOI: https://doi.org/10.1007/978-3-030-31866-6_100
  12. VITIU, A.,  CHIŞCA, D., GORINCIOI, E., COROPCEANU, E., BOUROSH, P. Synthesis and Biological Properties of the Novel Coordination Compound with Rhodanine-3-Acetic Acid. Proceedings of the 4th International Conference on Nanotechnologies and Biomedical engineering (ICNMBE-2019), September 18-21, 2019, Chisinau, Moldova, vol. 77, pag. 713-718.
  13. КОВАЛЕВ, В., КОВАЛЕВА, О., НЕННО, В. Комбинированный энергоэффективный процесс получения биогаза. В: Hydropower Impact on River Ecosystem Functioning. Proc. Intl. Conf. Eco-TIRAS, Tiraspol, Moldova, Oct 2019, pp. 156-159. ISBN 978-9975-56-690-2.
  14. КОВАЛЕВА, О., КОВАЛЕВ, В., НЕННО, В. Новые биохимические процессы для улучшения состояния природных водных экосистем. В: Hydropower Impact on River Ecosystem Functioning. Proc. Intl. Conf. Eco-TIRAS, Tiraspol, Moldova, Oct 2019, pp. 160-164. ISBN 978-9975-56-690-2.
     

Patents

  1. COVALIOV, V.; SACHEVICI, V.; COVALIOVA, O.; RUSNAC, A.; POLESCHUK, Gh. Procedeu de deodorizare a deşeurilor organice.  Cerere de brevet MD a2020 0014. 2020-02-18.
  2. VITIU, A., CHIŞCA, D., GORINCIOI, E., COROPCEANU, E.,  BOUROSH. Compus al zincului de tip polimer coordinativ cu ligand nou obținut prin condensare ce manifestă activitate antifungică şi antibacteriană. Brevet de invenție MD 4640. 2020-02-29.
  3. ARICU, A.; CUCICOVA, C.; SECARA, E.; BARBA, A.; UNGUR, N. Compusul 13-amino-14,15-dinorlabd-8(9)-enă pentru utilizare în calitate de remediu antimicotic. Hotărâre nr. 8984 din 02.04.2018.
  4. ARICU, A.; CUCICOVA, C.; DUCA, Gh.; SECARA, E.; BARBA, A.; UNGUR, N.; SPENGLER, G. Efectul antiproliferativ şi citotoxic al 1-(4-((4aS,8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)butan-2-yl)guanidinei. Cerere de brevet de invenţie  Nr de depozit a 2018 0006, data de depozit 02.14.2018.
  5.  ARICU, A.; CUCICOVA, C.; DUCA, Gh.; SECARA, E.; BARBA, A.; UNGUR, N.; SPENGLER, G.  Efectul antiproliferativ și citotoxic al N-Carbamimidoyl-2-((8aS)-2,5,5,8a-tetramethyl-3,4,4a,5,6,7,8,8a-octahydronaphthalen-1-yl)acetamidei(N-(D8,9-bicicloxomofar- nesenoil)-guanidina). Cerere de brevet de invenție  Nr de depozit a 2018 0007, data de depozit 02.14.2018. 
  6. ARICU, A.; CUCICOVA, C.; SECARA, E.; BARBA, A.; UNGUR, N. 13-amino-14,15-dinorlabd-8(9)-ena în calitate de remediu antimicotic. Cerere de brevet, 2017,  0089.
  7. CUCICOVA, C.; RUDIC, V.; ARÎCU, A.; CEPOI, L.; RUDI, L.; SECARA, E.; VALUŢA, A.; BARBĂ, A.; MISCU, V.; VLAD, P.; CHIRIAC, T. 1-(D8,13-Biciclohomofarnesenoil)-3-amino-1,2,4-triazolul şi procedeu de cultivare a cianobacteriei Nostoc linchia. Brevet de inventie, № 4327, BOPI 2015, (2), p. 27-28.
  8. CUCICOVA, C.; RUDIC, V.; ARÎCU, A.; CEPOI, L.; RUDI, L.; SECARA, E.; VALUŢA, A.; BARBĂ, A.; MISCU, V.; VLAD, P.; CHIRIAC, T. N-(D8,13-Biciclohomo- farnesenoilamino)-carbazolul şi procedeu de cultivare a cianobacteriei Nostoc linchia. Brevet de inventie, № 4326, BOPI 2015, (2), p. 26-27.
  9. MAŞCENCO, N.; LUPAŞCU, G.; GUREV, A.; BARBA, A.; GORINCIOI, E.; GAVZER, S. Procedeu de tratare a grâului de toamnă contra Fusarium oxysporum. Brevet de inventie, № 4327, BOPI 2015, (2), p. 27-28.
  10. ROBU, Şt.; PRISACARI, V.; KULCIŢKI, V.; GRINCO, M.; BARBA, A. Material polimeric cu proprietăţi antibacteriene pe bază de lignină grefată cu N'-(5-nitrofurfuriliden)izonicotinhidrazidă. Brevet de inventie, № 4506, BOPI 2017, (8), pag. 29.
  11. ARÎCU, A.; KUCHKOVA, K.; DUCA, Gh.; SECARA, E.; BARBA, A.; DRAGALIN, I.; UNGUR, N. Compusul 1-(4-((4aS,8aS)-2,5,5,8a-tetrametil- 3,4,4a,5,6,7,8,8a- octahidronaftalen 1-il)butan-2-il) guanidină cu activitate antiproliferativă şi citotoxică. Brevet de invenție, Nr. 4630, MD, BOPI 5/2019, p.41.
  12. ARÎCU, A.; KUCHKOVA, K.; DUCA, Gh.; SECARA, E.; BARBA, A.; DRAGALIN, I.; UNGUR, N. Compusul N-carbamimidoil-2-((8aS)-2,5,5, 8a-tetrametil-3,4,4a,5,6,7,8,8 aoctahidronaftalen-1-il)acetamidă cu activitate antiproliferativă şi citotoxică. Brevet de invenție, Nr. 4631, MD, BOPI 5/2019, p.41-42.

National projects

  1. ANCD/20.80009.5007.27. Physico-chemical mechanisms of redox processes with electron transfer involved in vital, technological and environmental systems
    Period: 2020-2023
    Project manager: Acad., dr. habilitate, prof. Gheorghe DUCA
     
  2. CSSDT/15.817.02.02F. Study of mechanisms of chemical reactions, electronic structure and physico-chemical properties of transitiom-metal coordination compounds and nanoparticles A2B6
    Period: 2015-2019
    Project manager: Dr., assoc. prof. Natalia GORINCIOI

International projects

  1. H2020/INFRADEV-02/DANUBIUS-RI/739562. Preparatory phase for the pan-european research infrastructure DANUBIUS–RI “International centre for advanced studies on river-sea systems”
    Period: 2016-2019
    Project manager: Acad., dr. habilitate, prof. Gheorghe DUCA