Laboratory of Coordination Chemistry

LCC
Head of the laboratory dr. habilitate, assoc. prof. Ion BULHAC
 

Office:  215
Phone: (+373 22) 73 96 11
Email: [email protected] 

 

             

                                    

Short history

The Laboratory of Coordination Chemistry is one of the oldest and most representative entities of the institute. The investigations in the field of chemistry of coordination compounds expanded substantially after the formation (in 1956) of the Department of Inorganic Chemistry of the Moldovan Branch of the Academy  of Sciences of the USSR. In 1975, the laboratory was called the Laboratory of Chemistry of Coordination Compounds, headed by acad. Antonie Ablov (during the years 1959-1978).

From 1978 till 2006 the head of the laboratory was acad. Nicolae Garbalau, for a short period (in 2006) the laboratory was guided by corr. mem. Mihail Revenco.
                                                                                                      

Research areas
  • Synthetic methods, especially template  synthesis  of the mono-, polynuclear and supramolecular compounds of the transition metals with organic polyfunctional ligands (oximes, carboxylic acids, Schiff bases, organic amines and other);
  • Basic research in elucidating physical, chemical, magnetic, catalytic and structural properties of the synthesized compounds, performed using physical methods: X-ray diffraction, NMR, IR and UV-Vis, Mössbauer, spectroscopy, photoluminescence, magnetochemistry, thermogravimetry;
    Applied  research  of  coordination  compounds  and  compozitions  based  on   these   compounds  as stimulators of the vital activity of some microorganisms and algae in the biosynthesis of enzymes, as well as stimulators for raising the productivity and drought resistance of cultivated plants;
  • Study of coordination processe, including template synthesis, usingpolidentateand„crown” coordinating agents for obtaining coordination compounds of various nuclearity and polymeric materials with programmed properties of biostimulators, catalysts, inhibitors, photo- and thermostable pigments, adsorbent materials and photoluminescent, for agriculture, biology, microbiology, technique, microelectronics and others.
Staff
Recent publications
Research projects

Ion BULHAC
dr. habilitate, assoc. prof.
Head of the laboratory

office 215
phone: (+373 22) 73 96 11
email: [email protected]; [email protected]

Anastasia STEFIRTA
dr. habilitate, prof. 
Principal scientific researcher

office 211
phone: (+373 22) 73 96 11
email: [email protected]

Maria COCU
dr., assoc. prof.
Leading scientific researcher

office 203; 325
phone: (+373 22) 73 99 63
email: [email protected]; [email protected]

Pavlina BOUROSH
dr., assoc. prof.
Leading scientific researcher

office 210
phone: (+373 22) 73 81 54
email:  [email protected]

Vera ZUBAREVA
dr.
Senior scientific researcher

office 212
phone: (+373 22) 73 96 11
email: [email protected]; [email protected]

Olga DANILESCU
dr.
Senior scientific researcher

office 209
phone: (+373 22) 73 96 11
email: [email protected]; [email protected]

Lilia BRINZA
dr., assoc. prof.
Senior scientific researcher

office 211
phone: (+373 22) 73 96 11
email: [email protected]

Lidia CUBA
Scientific researcher

office 206
phone: (+373 22) 73 96 11
email: [email protected]

Vasile LOZOVAN
dr.
Scientific researcher

office 202
phone: (+373 22) 73 96 11
email: [email protected] ; [email protected]

Dumitru URECHE
Scientific researcher
PhD student

office 204
phone: (+373 22) 73 96 11
email: [email protected]; [email protected]

Tatiana MITINA
Scientific researcher

office 131
phone: (+373 22) 73 99 77
email: [email protected]; [email protected]

Monographs

  1. COROPCEANU, E.; CILOCI, A.; ȘTEFÎRȚĂ, A.; BULHAC, I. Study of useful properties of some coordination compounds containing oxime ligands. Academica Greifswald, Germania. 2020. 266 p. ISBN 978-3-9402237-24-8.
  2. DRAGANCEA, Diana. Chimie supramoleculară. Curs de lecții, masterat. Chișinău, 2018, 75 p
     

Articles in international journals (SCOPUS and with IF)

  1. DANILESCU Olga, BOUROSH Paulina, PETUHOV Oleg, KULIKOVA Olga BULHAC, Ion, CHUMAKOV Yurii, CROITOR Lilia. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules. In:  Molecules, 2021, Volume 26, Issue 8, p. 2317. DOI: https://doi.org/10.3390/molecules26082317 (IF: 3,267).
  2. CROITOR, Lilia; COCU, Maria; BULHAC, Ion, BOUROSH, Paulina; KRAVTSOV, Victor; PETUHOV, Oleg; DANILESCU, Olga. Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn(II) with dihydrazone Schiff bases: Preparation, structure and thermal behavior. Polyhedron 206 (2021) 115329. https://doi.org/10.1016/j.poly.2021.115329 (IF:3,052).
  3. КОРОПЧАНУ, Э.Б.; УРЕКЕ,  Д.; РИЖА, А.П.; ЧИЛОЧИ, А.А.; КЛАПКО,С.Ф.; ДВОРНИНА, Е.Г.;  БУЛХАК, И.И.; КОКУ, M.A.; БОУРОШ, П.Н. Cинтез и строение комплексных соединений никеля(II) на основе дианилинглиоксима. Стимулирующие протеолитические свойства [Ni(DAnH)2]·0.25H2O. Коорд. Химия, т. 47, №: 1, 2021, cтр. 21-29.
    b) Coropceanu, E.B.; Ureche, D.; Rija, A.P.; Ciloci, A.A.; Clapco, S.F.; Dvornina,  E. G.:  Bulhac, I. I.; Cocu, M.A. and Bourosh, P.N. Synthesis and Structures of Nickel(II) Complexes Based on Dianilineglyoxime. Stimulation of the Proteolytic Properties by [Ni(DAnH)2]·0.25H2O. Russian Journal of Coordination Chemistry, 2021, Vol. 47, No. 1, pp. 17–25.
  4. DANILESCU, O., BULHAC, I., SHOVA, S., NOVITCHI, G., BOUROSH, P. Synthesis, structure and properties of coordination compounds of copper(II) with Schiff bases, obtained on the base of aromatic carbonyl compounds and hydrazides of carboxylic acids. In: Russian Journal of Coordination Chemistry. 2020, vol. 43(1), pp. 21-36.
  5. V. LOZOVAN, V. Ch. KRAVTSOV,  E. B. COROPCEANU, V. SIMINEL, O. V. KULIKOVA,  N. V. COSTRIUCOVA, M. S. FONARI , Water-sulfate anion interplay in the evolution of solid state architectures and emission properties of Zn and Cd coordination networks with four azine ligands, Journal of Solid State Chemistry, 2020,  286, p. 121312
  6. V. LOZOVAN, V. Ch. KRAVTSOV,  E. GORINCIOI, A. ROTARU, E. B. COROPCEANU, V. SIMINEL, M. S. FONARI,  Chromism, positional, conformational and structural isomerism in a series of Zn(II) and Cd(II) coordination polymers based on methylated azine N,N’-donor linkers. Polyhedron, 2020, 180, p.114411.
  7. CHISCA, D.; CROITOR L.; COROPCEANU E.; PETUHOV O.; VOLODINA G.; BACA S.; KRÄMER K.; HAUSER J.; DECURTINS S.; LIU S.-X.; FONARI M. Six Flexible and Rigid Co(II) Coordination Networks with Dicarboxylate and Nicotinamide-Like Ligands: Impact of Noncovalent Interactions in Retention of Dimethylformamide Solvent. Cryst. Growth Des., 2016, 16, 7011−7024. (IF: 4,425).
  8. CHISCA, D.; CROITOR, L.; COROPCEANU, E.; PETUHOV, O.; BACA, S.; KRÄMER, K.; LIU, S.; DECURTINS, S.J.; RIVERA-JACQUEZ, H.; MASUNOV, A.; FONARI,  M. From Pink to Blue and Back to Pink Aga Changing the Co(II) Ligation in a Two-Dimensional Coordination Network upon Desolvation.  CrystEngComm., 2016, 18, p. 384-389. ISSN 1466-8033. (IF: 4.034).
  9. CHISCA, D.; CROITOR, L.; PETUHOV, O.; COROPCEANU, E.; FONARI, M. MOF-71 as a degradation product in single crystal to single crystal transformation of new three-dimensional Co(II) 1,4-benzenedicarboxylate. CrystEngComm., 2016, 18, p. 38-41. ISSN 1466-8033. (IF: 4.034).
  10. CHISCA, D.; CROITOR, L.; PETUHOV, O.; KULICOVA, O.; VOLODINA, G.; COROPCEANU, E.; MASUNOV, A.; FONARI, M. Tuning Structures and Emissive Properties in a Series of Zn(II) and Cd(II) Coordination Polymers Containing Dicarboxylic Acids and Nicotinamide Pillars.  CrystEngComm., 2018, 20, P. 432-447. (IF: 3,474).
  11. COROPCEANU. E.; RIJA, A.; LOZAN, V.; BULHAC, I.; DUCA, GH.; KRAVTSOV, V.;  BOUROSH, P. Discrete Binuclear Cobalt(III) Bis-dioximates with Wheel-and-Axle Topology as Building Blocks To Afford Porous Supramolecular Metal−Organic Frameworks.  Crystal Growth & Design, 2016, 16, p. 814-820. ISSN 1528-7483. (IF: 4,425).
  12. CROITOR, L.; COROPCEANU, E.; PETUHOV, O.; KRAMER, K.; BACA, S.; LIU, S.-X.; DECURTINS, S.; FONARI, M. A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: structure and magnetic properties.  Dalton Transactions, 2015, 44, 7896–7902, ISSN: 1477-9226, 1477-9234 (IF: 4,09).
  13. CROITOR, L.; GRABCO, D.; COROPCEANU, E.; PYRTSAC, C.; FONARI, M. The softness of one-dimensional coordination polymer catena-{(adipato-O,O')-bis(pyridine-4-aldoxime)-copper(II)} under mechanical loads. CrystEngComm.,  2015, 17, p. 2450-2458, ISSN: 1466-8033 (Electronic) 1466-8033 (Linking) ( IF: 3,85).
  14. DRAGANCEA, D.; TALMACI, N.; SHOVA, S.; NOVITCHI, GH.; DARVASIOVA, D.; RAPTA, P.; BREZA, M.; GALANSKI, M.; KOZISEK, J.;  MARTINS, N. M. R. L., MARTINS, M. D. R. S.; POMBEIRO, A. J. L.; ARION, V. B. Electronic structure of oxido- and/or dioxidovanadium units in two different but closely related families of complexes with substituted 1,5-bis(2-hydroxybenzaldehyde)carbohydrazones and their use as catalyst precursors in oxidation of cyclohexane.  Inorg. Chem., 2016, 55, 9187−9203. (IF: 4,82).
  15. MELNIC, E.; COROPCEANU, E.; FORNI, A.; CARIATI, E.; KULIKOVA, O.; SIMINEL, A.; KRAVTSOV, V.;  FONARI, M. Discrete Complexes and One-Dimensional Coordination Polymers with [Cu(II)(2,2′-bpy)]2+ and [Cu(II)(phen)]2+ Corner Fragments: Insight into Supramolecular Structure and Optical Properties. Crystal Growth & Design, 2016, 16, p. 6275−6285. ISSN 1528-7483. (IF: 4,42).
  16. COROPCEANU, E.; CROITOR, L.; SIMINEL, A.; CHUMAKOV, YU.; FONARI, M. The luminescence attenuation in the solid state by fluoride anion entrapped in the one-dimensional Zn(II) dioximate and mononuclear Cd(II) dioxime.  Polyhedron, 2016, 109, p. 107-114. ISSN 0277-5387. (IF: 2,108).
  17. CROITOR, L.; CHISCA, D.; COROPCEANU, E.; VOLODINA, G.; PETUHOV, O.; FONARI, M. Solvent-rich layered cobalt(II) 1,4-benzenedicarboxylate based on binuclear {Co2(m-OH2)(RCOO)2} secondary buiding unit.  Journal of  Molecular Structure, 2017, 1137, p. 136-141. ISSN 0166-1280  (IF: 1,71).
  18. CROITOR, L.; COROPCEANU, E.; DUCA, Gh.; SIMINEL, A.; FONARI, M. Nine  Mn(II), Zn(II) and Cd(II) mixed-ligand coordination networks with rigid dicarboxylate and pyridine-n-aldoxime ligands: impact of the second ligand in structures’ dimensionality and solvent capacity.  Polyhedron.  2017, 129, 9-21. ISSN 0277-5387. (IF: 2,108.)
  19. LOZOVAN, V.; KRAVTSOV, V.CH.; COROPCEANU, E.B.; ROTARU, P.; SIMINEL, A.V.; FONARI, M.S. Binuclear and polymeric Zn(II) and Cd(II) coordination compounds with chromophore N-((pyridin-4-yl)methylene)benzene-1,4-diamine obtained in situ: Preparation, structural and spectroscopic study. Inorganica Chimica Acta. 2019, 491, 42-51. ISSN 0020-1693 (IF: 2,264)
  20. BORDIAN, OLGA; VERLAN, VICTOR; CULEAC, ION; IOVU, MIHAIL; ZUBAREVA, VERA; NISTOR, IURIE. Optical characterization of a new nanocomposite SBMA/Eu(TTA)3(Ph3PO)2.  Topics in Optoelectronics, Microelectronics, and Nanotechnologies  VII, 2015, doi: 10.1117/12.2069989 (8 pagini). ISSN (print): 2286-3540, ISSN (online): 2286-3559  (IF: 0,23).
  21. BORDIAN, O.; VERLAN, V.; CULEAC, I.; IOVU, M.; ZUBAREVA V. Photoluminescente properties of Eu(o-MBA)3 Phen organic compound embedded in PEPC polymer matrix.  Journal of Optoelectronics and Advanced Materials, 2017, 19(3–4),  p. 223 – 227. ISSN  1454-4164. (IF: 0,29).
  22. COROBET, A.; VITIU, A.; PETUHOV, O.; CROITOR, L. Sulfur extrusion and sulfur oxidation of 2,2′-dithiodibenzoic acid in combination with Cu(II) ion and in the absence of co-ligands: Structural, spectroscopic and thermogravimetric evidence. Polyhedron, 151, 2018, p. 51-57. DOI: 10.1016/j.poly.2018.05.013. (IF 1,92).
  23. KRAVTSOV, V. CH.; MALAESTEAN, I.; STINGACH, E. P.; DUCA, G. G.; MACAEV, F. Z.; VAN LEUSEN, J.; KOGERLER , P.; HAUSER, J.; KRAMER, K.; DECURTINS, S.; LIU, SHI-XIA; GHOSH, A. C.; GARCIA, Y.; BACA, S. G. Hexanuclear Fe(III) wheels functionalized by amino-acetonitrile derivatives.  Solid State Sciences, 2018, 78, 156-162. ISSN:1293-2558. (IF: 1.811).
  24. ŞTEFÎRŢĂ, A.; BOTNARI, V.; BRÂNZĂ, L.; BULHAC, I.; CHILINCIUC, A.L.. Agronomical biofortification of garlic plant (Allium sativum L.) in aspect of increasing selenium content and antioxidant properties.  Advansement in Medicinal Plant Rresearch, 2016, 4(3), pp.99-105, ISSN: 2354-2152. (IF: 0.641).
  25.  БУЛХАК, И.; ДАНИЛЕСКУ, О.; РИЖА, А.; ШОВА, С.; КРАВЦОВ, В.Х.; БОУРОШ, П.Н. Синтез и кристаллическая структура комплексов Со(П) с пентадентатными Шиффовыми основаниями 2,6-диацетилпиридингидразонов. Координационная химия, 2017, 43(1) 23-38 (rusă). ISSN 0132-344X. (IF:  0,541).
  26. BULHAC, I.; DANILESCU, O.; RIJA, A.; SHOVA, S.; KRAVTSOV, V.Ch.;    BOUROSH, P.N. Cobalt(II) Complexes with Pentadentate Schiff Bases 2,6-Diacetylpiridine Hydrazones: Syntheses and Structures.  Russian Journal of Coordination Chemistry. 2017, 43(1), p. 21-36. ISSN 1070-3284. (engleză) (IF: 0,541).
  27. БОУРОШ, П.;  БУЛХАК, И.; МЫРЗАК, А.; ШОВА, С.; ДАНИЛЕСКУ, О.. Синтез и строение моно- и биядерного комплексов ванадия с пентадентатным основанием  Шиффа 2,6-диацетилпиридин-бис(никотиноилгидразон).  Координационная химия, 2016, 42(3), с. 137-145. (IF: 0.516).
  28. БОУРОШ, П.; БУЛХАК, И.; КОВАЧ, О.; ЗУБАРЕВА, В.; МИТИНА, Т. Бис-α-Бензилдиоксиматные комплексы железа(II) с 3- и 4-пиридинполуацеталями в качестве аксиальных лигандов: синтез, строение и физико-химические свойства. Координационная химия, 2018, 44(4), 255-265 (FI: 0.717).
  29. BOUROSH, P.; BULHAC, I.; COVACI, O.; ZUBAREVA, V.; MITINA, T. Iron(II) Bis-α-Benzyldioximate Complexes with 3- and 4-Pyridine Hemiacetals as Axial Ligands: Synthesis, Structure, and Physicochemical Properties. Russian Journal of Coordination Chemistry, 2018, 44(8), pp. 507-517. ISSN 1070-3284.
  30. БОУРОШ, П.; БОЛОГА, О.; ДЕСЯТНИК-ЧИЛОЧИ, А.; ТЮРИНА, Ж.; БУЛХАК, И. Синтез и строение смешанных диоксиматов кобальта(Ш) с производными гуанидина и их биологические свойства.  Координационная химия. 2017, 43(9), c. 553-562. ISSN  0132-344X. (rusă). (IF:  0,541).
  31. BOUROSH, P.; BOLOGA, O.; DESEATNIC-CILOCI, A.; TIURINA, J.; BULHAC, I. Synthesis, Structure, and Biological Properties of Mixed Cobalt(III) Dioximates with Guanidine Derivatives.  Russian Journal of Coordination Chemistry, 2017, 43(9), p. 591-599. ISSN 1070-3284. (engleză). (IF: 0,541).
  32. ВИТИУ, А.А.; КОРОПЧАНУ, Э.Б.; БОУРОШ, П.Н. Cинтез и строение новых координационных полимеров Zn(II) и Co(II) с 1,3,5-бензолтрикарбоновой кислотой. Координационная химия, 2017, 43(11), c. 676-683. (IF:  0,541).
  33. ВИТИУ, А.А.; КОРОПЧАНУ, Э.Б.; БОУРОШ, П.Н. Новые координационные полимеры Zn(II) и Cd(II) с 1,2-бензолдикарбоновой кислотой: синтез и строение. Коорд. Химия. 2019, 45(2), 67–78. ISSN (PRINT) 0132-344X  (IF:0,674).
  34. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. New Zn(II) and Cd(II) Coordination Polymers with 1,2-Benzenedicarboxylic Acid: Synthesis and Structures. Russian Journal of Coordination Chemistry, 2019, 45(2), 81–91. ISSN (PRINT) 1070-3284 (IF:0,674).
  35. ВИТИУ, А.А.; КОРОПЧАНУ, Э.Б.; БОУРОШ, П.Н. Синтез и кристаллическая структура новых комплексов Сu(II) и Co(II) с 2-бензоилпиридином. Коорд. Химия. 2019, 45(11), 700-704. ISSN (PRINT) 0132-344X (IF:0,674).
  36. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. New Сu(II) and Co(II) Complexes with 2-Benzoylpyridine: Syntheses and Crystal Structures. Russian Journal of Coordination Chemistry. 2019, 45(11), 804–808. ISSN (PRINT) 1070-3284 (IF:0,674).
  37. ВИТИУ, A.A; КOРОПЧАНУ, Э.Б.; БОУРОШ, П.Н.  Синтез и кристаллическая структура α-диметилглиоксиматов Co(III) c имидазолом. Журнал структурной химии, 2017, 58(3), c. 571-576. ISSN: 0022-4766 ISSN: 1573-8779  doi 10.15372/JSC20170314 (IF: 0,536).
  38. КОРОПЧАНУ, Э.Б.; БОЛОГА, О.А.; АРСЕНЕ, И.; ВИТИУ, А.; БУЛХАК, И.И.; ГОРИНЧОЙ, Н.; БОУРОШ, П.Н. Cинтез и исследование продуктов внутрисферного замещения в азид-содержащих диоксиматах Сo(III).  Коорд. Химия, 2016,  42(8), с. 480-502. ISSN 0132-344X. (IF: 0,516).
  39. КОРОПЧАНУ, Э.Б.; БУЛХАК, И.; ШТЕФЫРЦЭ, А.А.; БОТНАРЬ, В.Ф.; МЕЛЕНЧУК, М.; КУЛИГИН, Е.; БОУРОШ, П.Н. Синтез, кристаллическая структура и биологические свойства комплекса [Co(DmgH)2(Seu)1.4(Se-Seu)0.1][BF4]. Координационная химия. 2017,.43(3), c. 156-163 (rusă) ISSN 0132-344X. (IF:  0,541).
  40. COROPCEANU, E.D.; BULHAC, I.; SHTEFYRTSE, A. A.; BOTNAR, V.F.; MELENCHUK, M.; KULIGIN, E.; BOUROSH, P.N. Synthesis, Crystal Structure, and Biological Properties of the Complex   [Co(DmgH)2(Seu)1.4(Se-Seu)0.1][BF4].  Russian Journal of Coordination Chemistry, 2017, 43(3), p. 164-171. ISSN 1070-3284. (engleză). (IF:  0,541).
  41. КОРОПЧАНУ, Э.Б.; КРОИТОР, Л.; ЧИЛОЧИ, А.А.; ТЮРИНА, Ж.П.; ДВОРНИНА, Е.Г.; КОДРЕАНУ, C. З.; ФОНАРЬ, М.С. Cинтез и строение моноядерных комплексов цинка с  пиридин-2-альдоксимом. Координационная химия, 2017, 43(5), c. 268-264. ISSN  0132-344X. (IF: 0,541).
  42. КОРОПЧАНУ, Э.Б.; КРОИТОР, Л.; ЧИЛОЧИ, А.А.; КЛАПКО, С.Ф.; ЛАБЛЮК, С.В.; КОДРЕАНУ, C.З.; ФОНАРЬ, М.С. Cинтез и исследование некоторых  1,2-циклогександиондиоксиминов цинка и кадмия. Координационная химия. 2017,.43(7), c. 399-406. ISSN  0132-344X. (IF: 0,541).
  43. КОРОПЧАНУ, Э.; РУДИК, В.; ЧЕПОЙ, Л.; РУДЬ, Л.; ЛОЗАН, В.; КИРИЯК, Т.; МИСКУ, В.; БУЛХАК, И.; КРАВЦОВ, В.; БОУРОШ, П. Синтез и структура [Co(DmgH)2(Thio)2]2F[PF6]. Влияние фторсодержащих диоксиматов Co(III) на физиологические процессы микроводоросли Porphyridium cruentum. Коорд. Химия. 2019, 45(3), 170–177. ISSN (PRINT) 0132-344X  (IF:0,674).
  44. COROPCEANU, E.; RUDIC, V.; CEPOI, L.; RUDI, L.; LOZAN, V.; CHIRIAC, T.; MISCU, V.; BULHAC, I.; KRAVTSOV, V.; BOUROSH, P. Synthesis and Crystal Structure of [Co(DmgH)2(Thio)2]2F[PF6]. The Effect of alga Porphyridium cruentum. In: Russian Journal of Coordination Chemistry. 2019, 45(3), 206–213. ISSN (PRINT) -3284 (IF: 0,674).
  45. ЛОЗОВАН, В.; КОРОПЧАНУ, Э.Б.; БОУРОШ, П.Н.; МИКУ, А.; ФОНАРЬ, М.C. Синтез, кристаллическая структура и люминесцентные свойства координационных полимеров Zn и Cd на основе двух изомерных азиновых лигандов. Коорд. Химия, 2019, 45(1), 13–23. ISSN (PRINT) 0132-344X   (IF:0,674).
  46. LOZOVAN, V.; COROPCEANU, E.; BOUROSH, P.; MICU, A.; FONARI, M. Coordination polymers of Zn and Cd based on two izomeric azinic ligands: synthesis, crystal structures and luminescent properties. Russian Journal of Coordination Chemistry, 2019, 45(1), 11–21. ISSN (PRINT) 1070-3284 (IF:0,674).
  47. УРЕКЕ, Д.; БУЛХАК, И.; РИЖА, А.; КОРОПЧАНУ, Э.; БОУРОШ, П. Синтез и структура соли дианилинглиоксима и его биядерных комплексов Zn(II) и Mn(II) с 1,3-бензолдикарбоновой кислотой. Координационная химия. 2019, 45(12), 720-733. ISSN (PRINT) 0132-344X (IF:0,674).
  48. URECHE, D.; BULHAC, I.; RIJA, A.; COROPCEANU E.; BOUROSH, P. Dianilineglyoxime Salt and Its Binuclear Zn(II) and Mn(II) Complexes with 1,3-Benzenedicarboxylic Acid: Synthesis and Structures. Russ. J. Coord. Chem. 2019, 45(12), 843-855. ISSN (PRINT) 1070-3284 (IF:0,674).
  49. DANILESCU Olga, BOUROSH Paulina, PETUHOV Oleg, KULIKOVA Olga BULHAC, Ion, CHUMAKOV Yurii, CROITOR Lilia. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules. In:  Molecules, Volume 26, Issue 8, p. 2317. DOI: https://doi.org/10.3390/molecules26082317 (IF: 3,267).
     

Articles in other international journals

  1. VALUŢA, A.; CEPOI, L.; RUDI, L.; BULHAC, I.; BOUROSH, P.; BOLOGA, O. Phycobiliprotein Accumulation in Cyanobacterium Mostoc Linckia and Modification of Antioxidant Activity.  Analele Universității din Oradea. Fascicula Biologie, V-XXII, 1, 2015, pp. 13-19.
  2. ȘTEFÎRȚĂ, A.; BOTNARI, V.; BRÂNZĂ, L.; BULHAC, I.; COROPCEANU, E.; BOUROSH, P.; CHILINCIUC, A. Possibilities of increasing the antioxidant properties of garlic plants (Allium Sativum, L.).  Acta Chemica Iași. 2017, 25(2), 208-231. DOI: 10.1515/achi-2017-0017. ISSN 2067 - 2438.


Articles in national journals

  1. BULHAC, I.; DESEATNIC-CILOCI, A.; BOUROSH, P.; TIURINA, J.; BOLOGA, O.; BIVOL, C.; CLAPCO, S.; VEREJAN, A.; LABLIUC, S.;  DANILESCU, O. Structure and some biological properties of Fe(III) complexes with nitrogen-containing ligands.    Chemistry Journal of Moldova, 2016, 11(1), p. 39-49. ISSN: 1857-1727.
  2. CUBA, L.; BOUROSH, P.; KRAVTSOV, V.; GORINCIOI, E.; DRAGANCEA, D. Oxido- and dioxidovanadium(V) complexes with o-vanillin semicarbazone: synthesis and crystal structure.  Chemistry Journal of Moldova, 2018, 13(1), p. 36-46, DOI: 
  3. DANILESCU, O. Structural study of mono- and binuclear 2,6-diacetylpyridine bis(nicotinoylhydrazone) coordination compounds. Moldavian Journal of the Physical Sciences, 2018, nr. 1-2,  p. 177-184. ISSN 1810-648X.
  4. GORINCHOY, V.; ZUBAREVA, V.; MELNIC, E.; KRAVTSOV, V. Heterotrinuclear [Fe2IIINiII]-µ3-oxo-cluster based on salicylic acid. Synthesis, structure and physico-chemical properties.  Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry, 13(1), 2018, p. 46-54. ISSN 1857-1727 (print), ISSN 2345-1688 (online).
  5. http://dx.doi.org/10.19261/cjm.2018.477 .   ISSN 1857-1727 (print), ISSN 2345-1688  (online).
  6. LUPAȘCU, T.; ARÎCU, A.; COCU, M.. Institutul de Chimie al AȘM – realizări și perspective.   Buletinul Academiei de Științe a Moldovei. Științele vieții,  2016, 1(328), pp. 184-200, ISSN 1024-7696.
  7. VITIU, A.; CROITOR, L.; SIMINEL, A.; COROPCEANU, E.; BOUROSH, P. A novel 2D zinc(II) coordination polymer based on 2,2'-bipyridine-4,4'-dicarboxylic acid: synthesis, crystal structure and photoluminescence property.  Chemistry Journal of Moldova, 2018, 13(1),  p. 30-35. ISSN 1857-1727 (print), ISSN 2345-1688 (online).
  8. VITIU, A.; Novel iron(II) and copper(II) polymeric coordination compounds with N,N′-bipyridine-type ligands: synthesis and characterization. Chemistry journal of moldova. General, Industrial and Ecological Chemistry. 2019, 14(1), 120-127. DOI: 10.19261/cjm.2019.569.
  9. БОЛОГА, О.А.; ПAРШУТИН, В.В.; ШОЛТОЯН,  Н.С.; КОВАЛЬ, А.В.;   ЧЕРНЫШЕВА, Н.В.; ВЕРЕЖАН, А.В.; БУЛХАК, И.И. Ингибирование коррозии Ст.3 в воде комплесным соединением – хлористый дигидразид семикарбазиддиуксусной кислоты никеля(П) тригидрат.  Электронная обработка материалов, том. 53, № 6, 2017. COCU, Maria; MANOLE, Ştefan. Coordination compounds of oxovanadium(IV)  based on S-methylisothiosemicarbazide as dyes for thermoplastic polymers.  Chemistry Journal of Moldova, 2015,10 (2), p. 64-70. ISSN: 1857-1727.
  10. BULHAC, I.; ȘTEFÎRȚĂ, A.; COROPCEANU, E. Compuși coordinativi și compoziții cu proprietăți utile pentru biotehnologii agricole.  Studia universitatis moldaviae, 2015, 1(81), 193-209. ISSN: 1857-1735.
  11. COROPCEANU, E. Evoluția de la compuși mono- spre polinucleari în baza unor liganzi monoximici.   Studia universitatis moldaviae. 2015, 1(81), 186-192. ISSN: 1857-1735.
  12. COVACI, Olga. α-Benzildioximați ai fierului(II) cu liganzi heterociclici ce conțin azot. Studia universitatis moldaviae. Seria “Științe reale și ale naturii“. 2018, 1(111). ISSN 1811 3237. ISSN online 1837 198X, p. 156-161.
  13. DESEATNIC-CILOCI, Alexandra; COROPCEANU, Eduard; CLAPCO, Steliana; RIJA, Andrei; TIURINA, Jana; BIVOL, Cezara; BOLOGA, Olga; BULHAC, Ion. Influenţa compuşilor coordinativi ai Co(III), Cu(II) şi Zn(II) cu liganzi oximici asupra biosintezei hidrolazelor exocelulare la fungii miceliali.  Studia Universitatis Moldaviae, 2014, nr. 6(76), 57-70.  ISSN: 1857-1735.
  14. MÎRZAC, A. Investigaţia compușilor coordinativi ai vanadiului si fierului în baza bis{(iso)nicotnoilhidrazone} – 2,6 – diacetilpiridinei prin studiul cu raze X și spectroscopia IR.  Studia Universitatis Moldaviae, 2015, 73 -76.
  15. ПАРШУТИНВ, В.; ШОЛТОЯН, Н.; КОВАЛЬ, А.; ЧЕРНЫШОВА, Н.; БОЛОГА, О.; БУЛХАК,  И.; СОКОЛОВ, В.; СОКОЛОВА, А.;  БОДЮ, В. Влияние карбогидразида на ингибирования коррозию стали  СТ. 3 в воде.  Ноосфера, 2016, 16, 126-135.
  16. ROTARU, Mihaela; COCU, Maria. Sinteza și studiul liganzilor și compusului coordinativ al oxovanadiului(IV) în baza hidrazidei acidului izonicotinic și S-metiltiosemicarbazidei.  Acta et Commentationes, seria Științe Exacte și ale Naturii,  2017, 1(3), 136-145.
     

Articles in abstract books

  1. BORDIAN, O.T.; VERLAN, V.I.; IOVU, M.; CULEAC, I.; ZUBAREVA V.E.;   MALAHOV, L.A. Synthesis and luminescent properties of ligand-Europium(III) Coordination compounds.  Proceeding of the International Conference on Microelectronics and Computer Science & the 6th Conference of Physicists of Moldova. October 19-21, 2017. Chișinău: UTM, p.126-129.
  2. BULHAC, I., DANILESCU, O. Compuși coordinativi ai unor metale tranziționale 3d cu baze Schiff heterociclice. Sinteză, structură, proprietăți. Învățământ superior: tradiții, valori, perspective” conferința științifică națională cu participare internaţională. 27-28 septembrie 2019, Chișinău, vol. I,  pp. 12-17.  ISBN 978-9975-76-284-7.
  3. BULHAC, I.; DESEATNIC-CILOCI, A.;  CUBA,  L.; BIVOL, C.; DANILESCU, O.; DVORNINA, E.; BOUROŞ, P. Compuşi coordinativi ai fierului(III) cu activitate biologică.  Proceedings of International Conference „Modern Technologies in the Food Industry”, 20-22 october, 2016 Chişinău, pp. 348-355.
  4. COROPCEANU, E.; CILOCI, A.; ŞTEFÎRŢĂ, A.; BULHAC, I. Compuşi coordinativi oximici în calitate de stimulatori ai proceselor fiziologice la unii fungi şi plante de cultură.  Proceedings of International Conference „Modern Technologies in the Food Industry”, 20-22 october 2016, Chişinău, pp. 369-374.
  5. CUBA, L, BOUROSH, P., DRAGANCEA, D.  Synthetic, spectroscopic and structural  studies of coordination compound of Ni(II) with o-vanillin semicarbazone.  Conferința Științifică cu Participare Internațională a Doctoranzilor „Tendințe contemporane ale dezvoltării științe: viziuni ale tinerilor cercetători”, 15 iunie 2017, Chisinau, UnASM, p. 116-120.
  6. CUBA, L. Compusul coordinativ al Ni(II) cu semicarbazonă 2,3-dihidroxibenzaldehidei.  Conferința științifică a doctoranzilor «Tendințe contemporane ale dezvoltării științei: viziuni ale tinerilor cercetători», ediția a VI-a, Moldova, Chișinău, 15 iunie 2018, volumul I, p.100-103.
     

Patents

  1. BULHAC Ion; DESEATNIC-CILOCI Alexandra; CUBA Lidia; TIURINA Jana;  BOUROŞ Polina;  DRAGANCEA Diana;  CLAPCO Steliana. Azotaţi de (2,3-butandiona-bis-(izonicotinoilhidrazo-nă)-tris-acua)fier(III) monohidraţi în calitate de stimulatori ai sin-tezei enzimelor proteolitice la cultivarea tulpinii de fungi miceliali Fusarium gibbosum CNMN FD 12. Patent 4509 C1 from 2018.03.31.
  2. BULHAC, I.; RUDIC, V.;  DRAGANCEA, D.; RUDI, L.;  ȘOVA, S.; CEPOI, L.; GUSINA, L.; MISCU, V.; CIOBOTARI, A.; CHIRIAC, T.; VALUŢA, A. Bis[N'-(2-hidroxi-kO- 3 -carboxibenziliden)piridin-3-carbohidrazidat(-1)-k2N ',O ]fier(III) perclorat - apă (4/5) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. Patent MD 4367 B1 from 2015.08.31.
  3. BULHAC, I.; RUDIC, V.;  DRAGANCEA, D.; RUDI, L.;  ȘOVA, S.; CEPOI, L.; GUSINA, L.; MISCU, V.; CIOBOTARI, A.; CHIRIAC, T.; VALUŢA, A. Bis[N'-(2-hidroxi-kO- 3 -carboxibenziliden)piridin-3-carbohidrazidat(-1)-k2N ',O ]fier(III) perclorat - apă (4/5) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. Patent MD 4367 B1 from 2015.08.31.
  4. CILOCI, A., TIURINA, J., BULHAC, I., DANILESCU, O., LABLIUC, S., DVORNINA, E. Mediu nutritiv pentru cultivarea tulpinii de fungi Fusarium gibbosum CNMN FD 12. Patent MD 4645 B1 from 2019.08.31
  5. COCU, M.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUTIUM, V.; CEPOI, L.; MISCU, V.; CHIRIAC, T.; DJUR, S. Compusul coordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1,6-diolato(-2)-O1,N4,O6 ]fier(III) nitratşi utilizarea lui în calitate de stimulator al biosintezei componentelor fenolice de către microalga Porphyridium cruentum. Patent MD 4365 B1 from 2015.08.31
  6. COCU, M.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUTIUM, V.; CEPOI, L.; BALAN, C.; MISCU, V.; CHIRIAC, T.; GHELBET, V. Compusul coordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1-hidroxi-6-olato(-2)-O1,N4,O6]fier(II) sulfattetrahidratşi utilizarea lui în calitate de stimulator al biosintezei componentelor fenolice de către microalga Porphyridium cruentum. Patent MD 4366 B1 from 2015.08.31
  7. COCU, Maria; MANOLE, Ştefan. Colorant pentru polimerii termoplastici.  Brevet MD 4328 B1. Eliberat la 2015.02.28
  8. COCU, Maria; RUDIC, Valeriu; BULHAC, Ion; RUDI, Ludmila; GUTIUM, Victoria; CEPOI, Liliana; MISCU, Vera; CHIRIAC, Tatiana; DJUR, Svetlana. Compusul   coordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1,6-diolato(-2)-O1,N4,O6 ]fier(III) nitrat şi utilizarea lui în calitate de stimulator al biosintezei componentelor fenolice de către microalga Porphyridium cruentum. Patent MD 4365 B1 from 2015.08.31
  9. COCU, Maria; RUDIC, Valeriu; BULHAC, Ion; RUDI, Ludmila; GUTIUM, Victoria; CEPOI, Liliana; BALAN, Cristina; MISCU, Vera; CHIRIAC, Tatiana; GHELBET, Viorica. Compusul coordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1-hidroxi-6-olato(-2)-O1,N4,O6]fier(II) sulfat tetrahidrat şi utilizarea lui în calitate de stimulator al biosintezei componentelor fenolice de către microalga Porphyridium cruentum. Patent MD 4366 B1 from 2015.08.31
  10. COROPCEANU, E.; PARŞUTIN, V.; ŞOLTOIAN, N.; CERNÎŞEVA, N.; COVALI, A.; CROITOR, L.; BULHAC, I.; BOLOGA, O.; FONARI, M. Inhibitor al coroziunii oțelurilor în apă. Patent MD 4330 from 2015.09.30.
  11. DRAGANCEA, D.;  RUDIC, V.;  BULHAC, I.; RUDI, L.; GUSINA, L.; CEPOI, L.; CIOBOTARI, A.; MISCU, V.; CHIRIAC, T.; SADOVNIC, D. Bis[N'-(2-hidroxi-kO- benziliden)piridin-4-carbohidrazidat(-1)-k2N',O ]fier(III) nitrat - apă (2/3) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. Patent MD 4356 B1 from  2015.07.31.
  12. DRAGANCEA, D.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUSINA, L.; CEPOI, L.; CIOBOTARI, A.; MISCU, V.; CHIRIAC, T.; SADOVNIC, D. Bis[N'-(2-hidroxi-kO- benziliden)piridin-4-carbohidrazidat(-1)-k2N',O ]fier(III) nitrat - apă (2/3) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. Patent MD 4356 B1 from 2015.07.31.
  13. GUSINA, Liudmila; RUDIC, Valeriu; DRAGANCEA, Diana; CEPOI, Liliana; BULHAC, Ion; RUDI, Liudmila; MISCU, Vera; CHIRIAC, Tatiana; SADOVNIC, Daniela. Bis(dimetilglioximato)cloro (izonicotinoilhidrazonă 2-hidroxi-1-naftaldehidă) –(cobalt(III) şi procedeu de cultivare a microalgei Porphyridium cruentum. Patent MD 4303 from 2015. 04.30.
  14. MÎRZAC, A.; GUŢUL, T.; ZUBAREVA, V.; BULHAC, I.; MICU, A.; SIMINEL, A. Procedeu de obţinere a nanocompozitului CdSe/ZnS/PVP. Patent MD 4380 Cl from 2015.11.30, BOPI no.11/2015.
  15. PARŞUTIN Vladimir; ŞOLTOIAN Nicolae; CERNÎŞEVA Natalia; COVALI Alexandr; COROPCEANU Eduard; BULHAC Ion. Inhibitor de coroziune a oţelului în apă. Patent MD 1257 from 2019-01-31.
  16. PARȘUTIN, V.; ȘOLTOIAN, N.; CERNÎȘEVA, N.; COVALI, A.; COROPCEANU, E.; BULHAC, I. Inhibitor de coroziune a oțelului în apă. Patent MD 1257 Y from 2018.05.31.
  17. ŞTEFÂRŢĂ, A.; BULHAC, I.; BOTNARU, V.; MILENCIUC, M.; BUCEACI, S.; BOLOGA, O.; CIOBĂNICĂ,   O.; COROPCEANU, E. Procedeu de cultivare a sfeclei roşii Beta vulgaris L. Patent MD 813 BSD from 2015.04.30.   
  18. ŞTEFÎRŢĂ, A.; BOTNARI, V.; BULHAC, I.;    BRÂNZĂ, L.;  CHILINCIUC, A.; COROPCEANU, E.; BOUROŞ, P. Procedeu de cultivare a usturoiului. Patent MD 1087 from 2017.06.30.
  19. VITIU, A.; CHIȘCA, D.; GORINCIOI, E.; COROPCEANU, E.; BOUROȘ, P. Compus coordinativ polimeric al zincului cu ligand nou obținut prin condensare, care manifestă activitate antifungică și antibacteriană. Patent MD 4640. from 2019.07.31.
  20. VITIU, A.; CROITOR, L.; SIMINEL, A.; COROPCEANU, E.; BOUROȘ, P. Compus coordinativ polimeric al cadmiului(II) cu acidul 2-hidroxi-5-[[4-[(2-piridinilamino)sulfonil]fenil]azo]benzoic și 1,2-bis(4-piridin)etan care manifestă activitate luminiscentă. Patent MD 4597 from 2019-06-30.
  21. ȘTEFÎRȘĂ, A.; BRÎNZĂ L.; BULHAC, Ion; COROPCEANU, E.; BUCEACEAIA, S.; IONAȘCU, A.; COVACI, O. Procedeu de cultivare a plantelor de cultură. Patent MD 1348 Y from 2019. 07.31.

National projects

  1. ANCD/20.80009.5007.28. Elaboration of new multifunctional materials and efficient technologies for agriculture, medicine, technics and educational system based on the "s" and "d" metals complexes with polydentate ligands
    Period: 2020-2023
    Project manager: Dr. habilitate, assoc. prof. Ion BULHAC
     
  2. CSSDT/15.817.02.18A. Assembly and study of transition metal complexes based on polyfunctional and macrocyclic ligands useful for agriculture, food industry and advanced biotechnologies
    Period: 2015-2019
    Project manager: Dr. habilitate, assoc. prof. Ion BULHAC

  3. CSȘDT/16.00353.50.03A. Molecular and supramolecular architectures of lanthanides for magnetic applications
    Period: 2016-2017
    Project manager: Dr., assoc. prof. Diana DRAGANCEA

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