Synthesis and utilization of high-conductivity multifunctional nano-oligomers

Programme

STIMULATING EXCELLENCE IN SCIENTIFIC RESEARCH 2025-2026

Strategic priority

V. Innovative technologies, sustainable energy, digitization

Strategic direction

Fundamental research in physics, chemistry, mathematics

Code
25.80012.5007.72SE
Duration
01.08.2025-31.12.2026
Institutions

Institute of Chemistry, MSU

Laboratories/Centers

Laboratory of Organic Synthesis, Institute of Chemistry, MSU

Abstract

The project proposes the synthesis and characterization of new multifunctional nano-oligomers with high electricalconductivity, obtained through the oxidative polycondensation of aromatic amines and phenols (methyl-aniline, 2,6-dimethylaniline, diaminobenzene, phenol, dihydroxyphenols). Conductive nanopolymers have promising applications inelectronics, sensors, and advanced materials due to their superior electrochemical and mechanical properties. In recentyears, significant attention has been given to studying the oxidative polycondensation of aromatic amines, particularlyregarding the investigation and preparation of electrically conductive or antistatic polymer compositions containinginterconnected polyfunctional high-molecular-weight compounds. This project aims to develop innovative materials thatcontribute to technological and scientific advancements in the field of electroactive materials. In contrast to conventionalmethods, the project proposes the use of ultrasonic waves to optimize the oxidative polycondensation process, whichmay improve the structural homogeneity and conductivity of the obtained materials. Additionally, the interaction ofnanopolymers with metal ions and epoxy compounds will be investigated, potentially opening new directions in thedevelopment of functional nanocomposites. The project methodology is structured into two major stages, each includingspecific activities for the synthesis, characterization, and optimization of high-conductivity polymeric materials. Stage I –Determining the optimal conditions for obtaining nano-oligomers under ultrasonic waves (this stage aims to synthesizeand characterize multifunctional nano-oligomers by optimizing reaction parameters). Stage II – Determining the optimalconditions for obtaining electroactive nanocomposites under ultrasonic waves (this stage focuses on fabricating andtesting electroactive nanocomposites based on the synthesized nano-oligomers). As a result of these stages, at least 20types of nano-oligomers and at least 30 types of electroactive nanocomposites will be synthesized via oxidativepolycondensation using ultrasonic waves. The optimal reaction parameters (temperature, time, reagent ratio) for obtainingmaterials with desired properties will be determined, and the structure, morphology, and conductivity of the synthesizednano-oligomers and nanocomposites will be characterized. The results will be disseminated through the publication of atleast one article in SCOPUS- or WoS-indexed journals and presentations at international conferences. The project will beimplemented by a multidisciplinary team with expertise in materials chemistry, polymer synthesis, and the characterizationof electroactive structures. The outcomes will contribute to advancing knowledge in functional materials and will have asignificant impact on industry and applied research.