Bourosh Pavlina

Title Doctor, assoc. prof.
Position Leading scientific  researcher
Laboratory Coordination Chemistry
Office  209-Inst. Chem., 106-Inst. Appl. Phys.
Phone/fax (+373 22) 73 81 54
Email [email protected]
[email protected]
Professional links

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ORCID
Scopus Author ID
Instrumentul Bibliometric Național
AGEPI
Research areas

The area of scientific interest includes the X-rays study and solid state chemistry of coordination compounds, especially complex compounds of transition metals with organic ligands (oxime, carbaxylates, thio- and semicarbazides, ligands containing N, O, S donor atoms, including bridge function ) and some organic compounds, potential new ligands, and the structural study of organic salts, formed at the interaction of aromatic carboxylic acids with various aliphatic amines.

Relevant publications
Projects
  1. DANILESCU Olga, BOUROSH Paulina, PETUHOV Oleg, KULIKOVA Olga BULHAC, Ion, CHUMAKOV Yurii, CROITOR Lilia. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules. In:  Molecules, 2021, Volume 26, Issue 8, p. 2317. DOI: https://doi.org/10.3390/molecules26082317 (IF: 3,267).
  2. CROITOR, Lilia; COCU, Maria; BULHAC, Ion, BOUROSH, Paulina; KRAVTSOV, Victor; PETUHOV, Oleg; DANILESCU, Olga. Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn(II) with dihydrazone Schiff bases: Preparation, structure and thermal behavior. Polyhedron 206 (2021) 115329. https://doi.org/10.1016/j.poly.2021.115329 (IF: 3,052).
  3. КОРОПЧАНУ, Э.Б.; УРЕКЕ,  Д.; РИЖА, А.П.; ЧИЛОЧИ, А.А.; КЛАПКО,С.Ф.; ДВОРНИНА, Е.Г.;  БУЛХАК, И.И.; КОКУ, M.A.; БОУРОШ, П.Н. Cинтез и строение комплексных соединений никеля(II) на основе дианилинглиоксима. Стимулирующие протеолитические свойства [Ni(DAnH)2]·0.25H2O. Коорд. Химия, т. 47, №: 1, 2021, cтр. 21-29.
    b) Coropceanu, E.B.; Ureche, D.; Rija, A.P.; Ciloci, A.A.; Clapco, S.F.; Dvornina,  E. G.:  Bulhac, I. I.; Cocu, M.A. and Bourosh, P.N. Synthesis and Structures of Nickel(II) Complexes Based on Dianilineglyoxime. Stimulation of the Proteolytic Properties by [Ni(DAnH)2]·0.25H2O. Russian Journal of Coordination Chemistry, 2021, Vol. 47, No. 1, pp. 17–25.
  4. Crisan, M.E.; Vlase, G.; Vlase, T.; Croitor, L.Gh.; Bourosh, P.N.; Kravtsov, V.Ch.; Petric, M.F. Thermogravimetric and kinetic study of new bis(iminophosphorane)ethane solvates. J Therm Anal Calorim. 2020, 141(3), 1009—1016. Doi: 10.1007/s10973-020-09628-5 (IF: 2,471).
  5. Croitor, L.; Petric, M.F.; Vlase, G.; Vlase, T.; Siminel, A.V.; Bourosh, P.N.; Crisan, M.E. The solvent effect in obtaining of acid–base multicomponent systems: thermal, structural and luminescence study. J Therm Anal Calorim. 2020, 141(3), 973—979. Doi: 10.1007/s10973-020-09633-8 (IF: 2,471).
  6. Sumalan, R.L.; Croitor, L.; Petric, M.; Radulov, I.; Bourosh, P.; Sumalan, R.M.; Crisan, M. p-Aminobenzoate Organic Salts as Potential Plant Growth Regulators for Tomatoes. Molecules. 2020, 25(7), 1635-1—1635-15. Doi: 10.3390/molecules25071635 (IF: 3,060).
  7. Lozan, V.; Makhloufi, G.; Druta, V.; Bourosh, P.; Kravtsov, V.; Ch.; Marangoci, N.; Heering, Ch.; Janiak, Ch. Synthesis and structure of zinc(II) and cobalt(II) coordination polymers involving the elongated 2′,3′,5′,6′ tetramethylterphenyl-4, 4″-dicarboxylate ligand. Inorg Chim Acta. 2020, 506, 119500-1—119500-9. Doi: 10.1016/j.ica.2020.119500 (IF: 2,433).
  8. Vitiu, A.; Chişca, D.; Gorincioi, E.; Coropceanu, E.; Bourosh, P. Synthesis and Biological Properties of the Novel Coordination Compound with Rhodanine-3-Acetic Acid. În: IFMBE Proceedings, V. 77, Springer, 2020, p. 713—717. Doi: 10.1007/978-3-030-31866-6_126.
  9. LOZOVAN, V.; COROPCEANU, E.B.; BOUROSH, P.N.; MICU, A.; FONARI, M.S. Coordination Polymers of Zn and Cd Based on Two Isomeric Azine Ligands: Synthesis, Crystal Structures, and Luminescence Properties. Russ J Coord Chem. 2019, 45(1), 11—21. ISSN 1070-3284. doi 10.1134/S107032841901007X (IF: 0,636).
  10. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. New Zn(II) and Cd(II) Coordination Polymers with 1,2-Benzenedicarboxylic Acid: Synthesis and Structures. Russ J Coord Chem. 2019, 45(2), 81—91. ISSN 1070-3284. doi 10.1134/S1070328419020106 (IF: 0,636).
  11. COROPCEANU, E.; RUDIC, V.; CEPOI, L.; RUDI, L.; LOZAN, V.; CHIRIAC, T.; MISCU, V.; BULHAC, I.; KRAVTSOV, V.; BOUROSH, P. Synthesis and Crystal Structure of [Co(DmgH)2(Thio)2]2F[PF6]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum. Russ J Coord Chem. 2019, 45(3), 200—207. ISSN 1070-3284. doi 10.1134/S1070328419030059 (IF: 0,636).
  12. CRISAN, M.E.; GOROBET, A.; SIMINEL, A.V.; BOUROSH, P.N.; CROITOR, L. A new supramolecular isomer of p-aminobenzoate Zn(II) coordination polymer: Structure and photoluminescent property. Polyhedron. 2019, 171, 502—507. ISSN 0277-5387. doi 10.1016/j.poly.2019.07.042 (IF: 2,284).
  13. CROITOR, L.; PETRIC, M.F.; SZERB, E.I.; VLASE, G.; BOUROSH, P.N.; CHUMAKOV, Y.M.; CRISAN, M.E The role of 4-nitrobenzoic acid polymorphs in the crystallization process of organic acid–base multicomponent systems. Crystengcomm. 2019, 21(40), 6038—6047. ISSN 1466-8033. doi 10.1039/c9ce01239g (IF: 3,382).
  14. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. New Сu(II) and Co(II) Complexes with 2-Benzoylpyridine: Syntheses and Crystal Structures. Russ J Coord Chem. 2019, 45(11), 804—808. ISSN 1070-3284. doi 10.1134/S1070328419110101 (IF: 0,636).
  15. URECHE, D.; BULHAC, I.; RIJA, A.; COROPCEANU, E.; BOUROSH, P. Dianilineglyoxime salt and its binuclear Zn(II) and Mn(II) complexes with 1,3-benzenedicarboxylic acid: synthesis and structures. Rus J Coord Chem, 2019, 45(12), 843—855. ISSN 1070-3284. doi 10.1134/S107032841912008X (IF: 0,636).
  16. VODA, I.; MAKHLOUFI, G.; DRUTA,V.; LOZAN,V.; SHOVA, S.; BOUROSH, P.; KRAVTSOV,V.; JANIAK,Ch. Mixed-ligand coordination compounds based on the rigid 4,4′-bis(1-imidazolyl)biphenyl and pyridinedicarboxylate ligands. Inorg Chim Acta. 2018, 482, 526—534. ISSN 0020-1693. doi 10.1016/j.ica.2018.06.038 (IF: 2,264).
  17. CRISAN, M.; VLASE, G.; PLESU, N.; PETRIC, M.; CROITOR, L.; KRAVTSOV, V.; CHUMAKOV, Yu.; BOUROSH, P. ; VLASE, T. Ethylethanolammonium 4-nitrobenzoate: Synthesis, structural characterization, thermal analysis, non-isothermal kinetic investigations and corrosion inhibitor efficiency. J Therm Anal Calorim. 2018, 134(1), 343—352. ISSN 1388-6150. doi 10.1007/s10973-018-7296-6 (IF: 2,209).
  18. BOUROSH, P.; BULHAC, I.; COVACI, O.; ZUBAREVA, V.; MITINA, T. Iron(II) Bis-α-Benzyldioximate Complexes with 3- and 4-Pyridine Hemiacetals as Axial Ligands: Synthesis, Structure, and Physicochemical Properties. Russ J Coord Chem. 2018, 44(8), 507—517. ISSN 1070-3284. doi 10.1134/S1070328418080018 (IF: 0,674).
  19. GOROBET, A.; CRISAN, M.; PETRIC, M.; BOUROSH, P.; CROITOR, L. Structural study of Ca(II) coordination compound with triethanolamine and 4-nitrobenzoic acid. Rev Roum Chim. 2018, 63(12), 1175—1179. ISSN 0035-3930 (IF: 0,395).
  20. VITIU, A.; CROITOR, L.; SIMINEL, A.; COROPCEANU, E.; BOUROSH, P. A novel 2D zinc(II) coordination polymer based on 2,2'-bipyridine-4,4'-dicarboxylic acid: synthesis, crystal structure and photoluminescence property Chem J Mold. 2018, 13(1), 30—35. ISSN 1857-1727. Doi 10.19261/cjm.2017.479.
  21. CUBA, L.; BOUROSH, P.; KRAVTSOV, V.; GORINCIOI, E.; DRAGANCEA, D. Oxido-and dioxidovanadium(v) complexes with o-vanillin semicarbazone: synthesis and crystal structure. Chem J Mold. 2018, 13(1), 36—45. ISSN 1857-1727. Doi 10.19261/cjm.2018.
  22. BULHAC, I.; DANILESCU, O.; RIJA, A.; SHOVA, S.; KRAVTSOV, V.Ch.; BOUROSH, P. Cobalt(II) Complexes with Pentadentate Schiff Bases 2,6-Diacetylpyridine Hydrazones: Syntheses and Structures. Russ J Coord Chem. 2017, 43(1), 21—36. ISSN 1070-3284. doi 10.1134/S1070328417010018 (IF: 0,541).
  23. COROPCEANU, E.B.; BULHAC, I.; SHTEFYRTSE, A.A.; BOTNAR, V.F.; MELENCHUK, M.; KULIGIN, E.; BOUROSH, P.N. Synthesis, Crystal Structure, and Biological Properties of the Complex [Co(DmgH)2(Seu)1.4(Se-Seu)0.5(Se2)0.1][BF4]. Russ J Coord Chem. 2017, 43(3), 164—171. ISSN 1070-3284. doi 10.1134/S1070328417030046 (IF: 0,541).
  24. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. Crystal structure of Co(III) α-dimethylglyoximates with imidazole. J Struct Chem. 2017, 58(3), 526—531. ISSN 0022-4766. doi 10.1134/S0022476617030131 (IF: 0,472).
  25. BOUROSH, P.; BOLOGA, O.; DESEATNIC-CILOCI, A.; TIURINA, J.; BULHAC, I. Synthesis, Structure, and Biological Properties of Mixed Cobalt(III) Dioximates with Guanidine Derivatives. Russ J Coord Chem. 2017, 43(9), 591—599. ISSN 1070-3284. doi 10.1134/S1070328417090019 (IF: 0,541).
  26. VITIU, A.A.; COROPCEANU, E.B.; BOUROSH, P.N. Synthesis and Structure of New Zn(II) and Co(II) Coordination Polymers with 1,3,5-Benzenetricarboxylic Acid. Russ J Coord Chem. 2017, 43(11), 745—752. ISSN 1070-3284. doi 10.1134/S1070328417110100 (IF: 0,541).
  27. CRISAN, M.; HALIP, L.; BOUROSH, P.; CHICU, S, A.; CHUMAKOV, Yu. Synthesis, structure and toxicity evaluation of ethanolamine nitro/ chloronitrobenzoates: a combined experimental and theoretical study. Chem Central J. 2017, 11:129.  ISSN: 1752-153X (electronic version). doi.org/10.1186/s13065-017-0346-5 (IF: 1,027).
  28. ȘTEFÎRȚA A.A., BOTNARI V.F., BRÂNZĂ L.M., BULHAC I.I., COROPCEANU E.B., BOUROSH P.N., CHILINCIUC A.I. Possibilities of increasing the antioxidant properties of garlic plants. (Allium Sativum, L.). Acta Chemica Iasi, 2017, 25(2), 208-231. doi 10.1515./achi-2017-0017.
  29. SÎRBU, A.; SECU,M.;  BOUROŞ, P.; PALAMARCIUC, O. Sinteza şi Structura Compuşilor Coordinativi ai Cuprului(II) cu Tiosemicarbazona Aldehidei 5-(Metilentrimetilamoniu) Salicilice. Studia Universitatis Moldaviae (Seria Ştiinţe Reale și ale Naturii) . 2016, 16(96), 214—244. ISSN 1814-3237.
  30. COROPCEANU, E.; RIJA, A.; LOZAN, V.; BULHAC, I.; DUCA, Gh.; KRAVTSOV, V.Ch.; BOUROSH, P. Discrete Binuclear Co(III) bis-Dioximates with Wheel-and-axle Topology as Building Blocks to Afford Porous Supramolecular Metal-organic Frameworks. Cryst Growth Des. 2016, 16(2), 814—820. ISSN 1528-7483. doi 10.1021/acs.cgd.5b01402 (IF: 4,425).
  31. BOUROSH, P.; BULHAC, I.; MIRZAC, A.; SHOVA, S.; DANILESCU, O. Mono- and Dinuclear Vanadium Complexes with the Pentadentate Schiff Base 2,6-Diacetylpyridine Bis(nicotinylhydrazone): Synthesis and Structures. Russ J Coord Chem. 2016, 42(3), 157—165. ISSN 1070-3284. doi 10.1134/S1070328416030015 (IF: 0,516).
  32. COROPCEANU, E.; BOLOGA, O.; ARSENE, I.; VITIU, A.; BULHAC, I.; GORINCHIOY, N.; BOUROSH, P.  Synthesis and characterization of inner-sphere substitution products in azide-containing сobalt(III) dioximates. Russ J Coord Chem. 2016, 42(8), 516—538. ISSN 1070-3284. doi 10.1134/S1070328416070046 (IF: 0,516).
  33. BULHAC, I.; DESEATNIC-CILOCI, A.; BOUROSH, P.; TIURINA, J.; BOLOGA, O.; BIVOL, C.; CLAPCO, S.; VEREJAN, A.; LABLIUC, S.; DANILESCU, O. Structure and some biological properties of Fe(III) complexes with nitrogen-containing ligands. Chem J Mold. 2016, 11(1), 39—49. ISSN 1857-1727.
  34. VALUTA, A.; CEPOI, L.; RUDI, L.; BULHAC, I.; BOUROSH, P.; BOLOGA, O. Phycobiliprotein accumulation in cyanobacterium Nostoc linckia and modification of antioxidant activity. Analele Universităţii din Oradea, Fascicula Biologie. 2015, T. XXII, N 1, p. 13-19.


Patents

  1. Vitiu, A.; Chișca, D.; Gorincioi, E.; Coropceanu, E.; Bouroș, P. Compus coordinativ polimeric al zincului cu ligand nou obţinut prin condensare, care manifestă activitate antifungică şi antibacteriană. Patent MD 4640 C1 2020.02.29.
    Lazarescu, A.; Melnic, E.; Bouroş, P.; Zariciuc, E. Compus hidrazonic al acidului 4-formil-3-hidroxi-2-naftoic care manifestă activitate antimicrobiană. Patent  MD 4600 C1 2019.06.30.
  2. Vitiu, A.; Croitor, L.; Siminel, A.; Coropceanu, E.; Bouroş, P. Compus coordinativ polimeric al cadmiului (II) cu acidul 2-hidroxi-5-[[4-[(2-piridinilamino)sulfonil]fenil]azo]benzoic şi 1,2-bis(4-piridin)etan care manifestă activitate luminescentă. Patent MD 4597 C1 2019.06.30.

Naional projects

  1. ANCD/20.80009.5007.28. Elaboration of new multifunctional materials and efficient technologies for agriculture, medicine, technics and educational system based on the "s" and "d" metals complexes with polydentate ligands
    Period: 2020-2023
    Project manager: Dr. habilitate, assoc. prof. Ion BULHAC

  2. ANCD/20.80009.5007.15 Implementation of crystal engineering approach and X-ray crystallography for design and creation of hybrid organic/inorganic materials with advanced physical and biologically active functions
    Period: 2020-2023
    Project manager: Dr., assoc. prof. Victor KRAVTSOV

  3. CSSDT/15.817.02.06F Multifunctional oxychalcogenide and metaloorganic materials with advanced magnetic, absorptive and luminescent characteristics: synthesis, experimental study, modeling and applications
    Period: 2020-2023
    Project manager: Acad. Leonid KULYUK

  4. CSSDT/14.518.02.04A Crystal engineering approach for design and tuning the architecture of functional metal-organic materials
    Period: 2014-2015
    Project manager: Dr., assoc. prof. Victor KRAVTSOV

  5. CSSDT/16.00353.50.05A Design and directing of the architecture of functional metalorganic materials by applying crystal engineering
    Period: 2016-2017
    Project manager: Dr., assoc. prof. Victor KRAVTSOV

Bilateral projects

  1. CSSDT/ANCD 17.80013.8007.07Ua. Synthesis, properties, molecular and crystal structure of benzodiazepine and fibrinogen receptor ligands 
    Period: 2017-2018
    Project manager: Dr., assoc. prof. Victor KRAVTSOV
  2. CSSDT/ANCD 16.80013.5007.04/Ro. New non-toxic aromatic carboxylate derivatives with role in plant growth regulation: from synthesis and structural investigations to biological tests (CAREPLANT)
    Period: 2016-2018;
    Project manager: Dr., assoc. prof. Pavlina BOUROSH
  3. CSSDT/17.80013.8007.07Ua Synthesis, properties, molecular and crystal structure of benzodiazepine and fibrinogen receptor ligands (SARBEFIR)
    Period: 2017-2018
    Project manager: Dr., assoc. prof. Victor KRAVTSOV
     

International  projects

  1. SCOPES IZ73Z0_152404 MT1  Synthesis, Experimental and Theoretical Study of Bistable Magnetic Materials Based on 3d and 3d-4f Exchange Coupled Clusters: Prospects for Practical Applications
    Period: 2014-2017
    Project manager: Dr., assoc. prof. Svetlana BACA 
  2. AȘM-STCU/17.80013.8007.10/6245STCU. Innovative nanodimensional solid multicomponent pharmaceutical forms containing hexamincobalt (III) with antiviral and antibacterial properties.
    Period: 2017-2019;
    Project manager: Dr. habilitate, prof. Fliur MACAEV