Bulhac Ion

Title/degree: Doctor habilitate, assoc. prof.
Position: Head of the laboratory
Laboratory: Coordination Chemistry
Office:  215
Phone/fax: (+373 22) 73 96 11
Email: [email protected]
[email protected]
[email protected]
Professional links:

ORCID
Google Scholar
Scopus Author ID
Instrumentul Bibliometric Național
AGEPI

Research areas

Coordination chemistry, organic chemistry, biochemistry, plant physiology, microbiology, biologically active substances, biocatalysts, photoluminescence; physical research methods - magnetochemistry, X-ray study, IR-, NMR-, Mossbauer spectroscopy, thermogravimetry.

Relevant publications
Projects

 Monograph

  1. Coropceanu, E.; Ciloci, A.; Ștefîrță, A.; Bulhac, I. Study of useful properties of some coordination compounds containing oxime ligands. Academica Greifswald, Germania, 2020, 266 p. ISBN 978-3-9402237-24-8.
     

Articles

  1. BOUROSH, P.; COCU, M.; DANILESCU, O. and BULHAC I. Binuclear Vanadium(V) Complex with the Ligand Based on Isonicotinic Acid Hydrazide and 1-Phenyl-1,3-Butanedione: Synthesis and Crystal Structure. Russian Journal of Coordination Chemistry, 2023, vol. 49, no. 3, pp. 195–205.  Doi: 10.1134/S1070328423700409. (IF: 1,814)
  2. BOUROSH, P., COROPCEANU, E., RIJA, A., URECHE, D., CILOCI (DESEATNIC), A., CLAPCO, S., DVORNINA, E., LABLIUC, S., BULHAC, I. Synthesis and structures of disulfanilamideglyoxime and Ni(II) and Cu(II) complexes with this ligand stimulating the proteolytic properties of [Cu(DsamH2)3]SO4·5H2O. In: Russian Journal of Coordination Chemistry / Koordinatsionnaya Khimiya, 2022, vol. 1(48), pp. 41-51. DOI: https://doi.org/10.1134/S1070328422010018https://ibn.idsi.md/ro/vizualizare_articol/152502 (FI: 1,179).
  3. CHUMAKOV, Y.M., DANILESCU, O., BOUROSH, P.N., KULIKOVA, O.V., BULHAC, I., CROITOR, L. Metal ions impact on the isostructurality and properties of 2D coordination polymers. In: CrystEngComm, 2022, vol. 24, pp. 4430-4439. https://doi.org/10.1039/D2CE00444E  (FI: 3,545).
  4. DANILESCU, O., BULHAC, I., BOUROSH, P.N., CROITOR, L. Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone. In: Polyhedron. 2022, vol. 215, pp. 115679. https://doi.org/10.1016/j.poly.2022.115679; https://ibn.idsi.md/ro/vizualizare_articol/150193 (FI: 3,052).
  5. URECHE, D., BULHAC, I., SHOVA, S., BOUROSH, P. Pseudomacrocyclic bis(dianilineglyoxime)cobalt(III) complexes cations: Synthesis and structures. In: Russian  Journal of Coordination Chemistry, 2022, 48(6), pp. 333-343. DOI: https://doi.org/10.1134/S1070328422060070 (FI = 1,179).
  6. DANILESCU Olga, BOUROSH Paulina, PETUHOV Oleg, KULIKOVA Olga BULHAC, Ion, CHUMAKOV Yurii, CROITOR Lilia. Crystal Engineering of Schiff Base Zn(II) and Cd(II) Homo- and Zn(II)M(II) (M = Mn or Cd) Heterometallic Coordination Polymers and Their Ability to Accommodate Solvent Guest Molecules. In:  Molecules, 2021, Volume 26, Issue 8, p. 2317. DOI: https://doi.org/10.3390/molecules26082317 (IF: 3,267).
  7. CROITOR, Lilia; COCU, Maria; BULHAC, Ion, BOUROSH, Paulina; KRAVTSOV, Victor; PETUHOV, Oleg; DANILESCU, Olga. Evolution from discrete mononuclear complexes to trinuclear linear cluster and 2D coordination polymers of Mn(II) with dihydrazone Schiff bases: Preparation, structure and thermal behavior. Polyhedron 206 (2021) 115329. https://doi.org/10.1016/j.poly.2021.115329 (IF: 3,052).
  8. КОРОПЧАНУ, Э.Б.; УРЕКЕ,  Д.; РИЖА, А.П.; ЧИЛОЧИ, А.А.; КЛАПКО,С.Ф.; ДВОРНИНА, Е.Г.;  БУЛХАК, И.И.; КОКУ, M.A.; БОУРОШ, П.Н. Cинтез и строение комплексных соединений никеля(II) на основе дианилинглиоксима. Стимулирующие протеолитические свойства [Ni(DAnH)2]·0.25H2O. Коорд. Химия, т. 47, №: 1, 2021, cтр. 21-29.
    b) Coropceanu, E.B.; Ureche, D.; Rija, A.P.; Ciloci, A.A.; Clapco, S.F.; Dvornina,  E. G.:  Bulhac, I. I.; Cocu, M.A. and Bourosh, P.N. Synthesis and Structures of Nickel(II) Complexes Based on Dianilineglyoxime. Stimulation of the Proteolytic Properties by [Ni(DAnH)2]·0.25H2O. Russian Journal of Coordination Chemistry, 2021, Vol. 47, No. 1, pp. 17–25.
  9. VALUŢA, A.; CEPOI, L.; RUDI, L.; BULHAC, I.; BOUROSH, P.; BOLOGA, O. Phycobiliprotein Accumulation in CyanobacteriumMostocLinckia and Modification of Antioxidant Activity.  AnaleleUniversității din Oradea. FasciculaBiologie, V-XXII, 1, 2015, pp. 13-19.
  10. BULHAC, I.; ȘTEFÎRȚĂ, A.; COROPCEANU, E. Compușicoordinativișicompoziții cu proprietăți utile pentrubiotehnologiiagricole. Studia universitatis moldaviae, 2015, 1(81), 193-209. ISSN: 1857-1735.
  11. BOLOGA, O.; PARSHUTIN, V.;  SHOLTOIAN, N.; KOVAL, A.; CHERNYSHEVA, N.; BULHAC, I. Inhibition of Steel Corrosion in Natural Water by Carbohydraride. The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry". Book of abstracts, Chisinau, Mldova, October 8-9, 2015, p.43.
  12. COCU, Maria; BALAN, Cristina; BULHAC, Ion.  New nickel(II) coordination compound bazed onnicotinoyl and isonicotinoylhydrazones.   The XVII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry".  Book of abstracts, Chişinău, Moldova, October 7-9, 2015, p. 51.
  13. COROPCEANU, E.; BOLOGA, O.; АRSENE, I.; BULHAC, I.; GORINCIOI, N.; VITIU, A.; BOUROSH, P.Synthesis and structural characterization of products of substitution in some azide-containing Co(III) dioximates.  The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry". Book of abstracts, Chisinau, Moldova, October 8-9, 2015, P23, P. 52.
  14. CUBA, L.; MITINA, T.; MIRZAC, A.; BULHAC, I. Synthesis and IR spectroscopy study of iron and cobalt coordination compounds with 2,3 – butanedionebis(iso)nicotinoylhidrazone.  The XVIII-th International Conference “Physical Methods in Coordination Chemistry and Supramolecular Chemistry”. Book of Abstracts. Chişinău, Moldova, October 8 – 9, 2015, P – 92.
  15. DESEATNIC – CILOCI, A.; BULHAC, I.; BOLOGA, O.; TIURINA, J.; CLAPCO, S.; BIVOL, C.; DVORNINA, E.;  LABLIUC, S. Coordination Compounds of Zn and Mo with Macrocyclic Ligands Derived from 2.6 Diformil-4-methylphenol and their Biological Properties. The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry". Book of abstracts.Chisinau, Mldova, October 8-9, 2015, p. 49.
  16. MIRZAC, Alexandra; GUTUL, Tatiana; ZUBAREVA, Vera; BULHAC, ION. ElectroforeticDeposition  ofCdSe/ZnS/PVP Nanocomposite..  The XVIII-th International Conference "PhisicalMethods in Coordination and Supramolecular Chemistry". Book of abstracts. Chişinău, Moldova, October 8-9, 2015, P76, p. 105.
  17. BULHAC, I.; RUDIC, V.;  DRAGANCEA, D.; RUDI, L.;  ȘOVA, S.; CEPOI, L.; GUSINA, L.; MISCU, V.; CIOBOTARI, A.; CHIRIAC, T.; VALUŢA, A. Bis[N'-(2-hidroxi-kO- 3 -carboxibenziliden)piridin-3-carbohidrazidat(-1)-k2N ',O ]fier(III) perclorat - apă (4/5) şiprocedeu de cultivare a microalgei Porphyridiumcruentum cu utilizareaacestuia. Brevet de  invențieMD 4367 B1. Eliberat la 2015.08.31.
  18. COCU, M.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUTIUM, V.; CEPOI, L.; MISCU, V.; CHIRIAC, T.; DJUR, S. Compusulcoordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1,6-diolato(-2)-O1,N4,O6 ]fier(III) nitratşiutilizarealuiîncalitate de stimulator al biosintezeicomponentelorfenolice de către microalga Porphyridiumcruentum. Brevet de  invențieMD 4365 B1. Eliberat la 2015.08.31
  19. COCU, M.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUTIUM, V.; CEPOI, L.; BALAN, C.; MISCU, V.; CHIRIAC, T.; GHELBET, V. Compusulcoordinativ bis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1-hidroxi-6-olato(-2)-O1,N4,O6]fier(II) sulfattetrahidratşiutilizarealuiîncalitate de stimulator al biosintezeicomponentelorfenolice de către microalga Porphyridiumcruentum. Brevet de  invențieMD 4366 B1. Eliberat la 2015.08.31
  20. COCU, Maria; RUDIC, Valeriu; BULHAC, Ion; RUDI, Ludmila; GUTIUM, Victoria; CEPOI, Liliana; MISCU, Vera; CHIRIAC, Tatiana; DJUR, Svetlana. Compusulcoordinativbis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1,6-diolato(-2)-O1,N4,O6 ]fier(III) nitratşiutilizarealuiîncalitate de stimulator al biosintezeicomponentelorfenolice de către microalga Porphyridiumcruentum.Brevetdeinvenție MD 4365 B1. Eliberat la 2015.08.31
  21. COCU, Maria; RUDIC, Valeriu; BULHAC, Ion; RUDI, Ludmila; GUTIUM, Victoria; CEPOI, Liliana; BALAN, Cristina; MISCU, Vera; CHIRIAC, Tatiana; GHELBET, Viorica. Compusulcoordinativbis[1-fenil-3-metil-6-(piridinium-4-il)-4,5-diaza-hexa-1,3-dien-1-hidroxi-6-olato(-2)-O1,N4,O6]fier(II) sulfattetrahidratşiutilizarealuiîncalitate de stimulator al biosintezeicomponentelorfenolice de către microalga Porphyridiumcruentum. Brevet de  invenție MD 4366 B1. Eliberat la 2015.08.31
  22. COROPCEANU, E.; PARŞUTIN, V.; ŞOLTOIAN, N.; CERNÎŞEVA, N.; COVALI, A.; CROITOR, L.; BULHAC, I.; BOLOGA, O.; FONARI, M. Inhibitor al coroziunii oțelurilor în apă. Brevet de  invenție MD 4330. Eliberat la 2015.09.30.
  23. DRAGANCEA, D.;  RUDIC, V.;  BULHAC, I.; RUDI, L.; GUSINA, L.; CEPOI, L.; CIOBOTARI, A.; MISCU, V.; CHIRIAC, T.; SADOVNIC, D. Bis[N'-(2-hidroxi-kO- benziliden)piridin-4-carbohidrazidat(-1)-k2N',O ]fier(III) nitrat - apă (2/3) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. BrevetdeinvențieMD 4356 B1. Eliberat la 2015.07.31.
  24. DRAGANCEA, D.; RUDIC, V.; BULHAC, I.; RUDI, L.; GUSINA, L.; CEPOI, L.; CIOBOTARI, A.; MISCU, V.; CHIRIAC, T.; SADOVNIC, D.Bis[N'-(2-hidroxi-kO- benziliden)piridin-4-carbohidrazidat(-1)-k2N',O ]fier(III) nitrat - apă (2/3) şi procedeu de cultivare a microalgei Porphyridium cruentum cu utilizarea acestuia. Brevet de invenție MD 4356 B1. Eliberat la 2015.07.31.
  25. GUSINA, Liudmila; RUDIC, Valeriu; DRAGANCEA, Diana; CEPOI, Liliana; BULHAC, Ion; RUDI, Liudmila; MISCU, Vera; CHIRIAC, Tatiana; SADOVNIC, Daniela. Bis(dimetilglioximato)cloro (izonicotinoilhidrazonă 2-hidroxi-1-naftaldehidă) –(cobalt(III) şiprocedeu de cultivare a microalgeiPorphyridiumcruentum. Brevet de  invenție MD 4303. Eliberat la 2015. 04.30.
  26. MÎRZAC, A.; GUŢUL, T.; ZUBAREVA, V.; BULHAC, I.; MICU, A.; SIMINEL, A. Procedeu de obţinere a nanocompozituluiCdSe/ZnS/PVP. Brevet MD 4380 Cl din 2015.11.30, BOPI nr.11/2015.
  27. ŞTEFÂRŢĂ, A.; BULHAC, I.; BOTNARU, V.; MILENCIUC, M.; BUCEACI, S.; BOLOGA, O.; CIOBĂNICĂ,   O.; COROPCEANU, E. Procedeu de cultivare a sfecleiroşii Beta vulgaris L. Brevet de  invenție MD 813 BSD.  Eliberat la 2015.04.30.
  28. COROPCEANU. E.; RIJA, A.; LOZAN, V.; BULHAC, I.; DUCA, GH.; KRAVTSOV, V.;  BOUROSH, P. Discrete Binuclear Cobalt(III) Bis-dioximates with Wheel-and-Axle Topology as Building Blocks To Afford Porous Supramolecular Metal−Organic Frameworks.  Crystal Growth & Design, 2016, 16, p. 814-820. ISSN 1528-7483. (IF: 4,425).
  29. ŞTEFÎRŢĂ,A.; BOTNARI, V.; BRÂNZĂ,L.; BULHAC,I.; CHILINCIUC,A.L.. Agronomical biofortification of garlic plant (Allium sativum L.) in aspect of increasing selenium content and antioxidant properties.  Advansement in Medicinal Plant Rresearch, 2016, 4(3), pp.99-105, ISSN: 2354-2152. (IF: 0.641).
  30. БОУРОШ, П.;  БУЛХАК,И.; МЫРЗАК,А.; ШОВА,С.; ДАНИЛЕСКУ,О.. Синтез и строение моно- и биядерного комплексов ванадия с пентадентатным основанием  Шиффа 2,6-диацетилпиридин-бис(никотиноилгидразон).  Координационная химия, 2016, 42(3), с. 137-145. (IF: 0.516).
  31. КОРОПЧАНУ, Э.Б.; БОЛОГА, О.А.; АРСЕНЕ, И.; ВИТИУ, А.; БУЛХАК, И.И.; ГОРИНЧОЙ, Н.; БОУРОШ, П.Н. Cинтез и исследование продуктов внутрисферного замещения в азид-содержащих диоксиматахСo(III).  Коорд. Химия, 2016,  42(8), с. 480-502. ISSN 0132-344X. (IF: 0,516)
  32. BULHAC, I.; DESEATNIC-CILOCI, A.; BOUROSH, P.; TIURINA, J.; BOLOGA, O.; BIVOL, C.; CLAPCO,S.; VEREJAN,A.; LABLIUC,S.;  DANILESCU, O. Structure and some biological properties of Fe(III) complexes with nitrogen-containing ligands. Chemistry Journal of Moldova, 2016, 11(1), p. 39-49. ISSN: 1857-1727.
  33. ПАРШУТИНВ, В.; ШОЛТОЯН, Н.; КОВАЛЬ, А.; ЧЕРНЫШОВА, Н.; БОЛОГА, О.; БУЛХАК,  И.; СОКОЛОВ, В.; СОКОЛОВА, А.;  БОДЮ, В. Влияние карбогидразиданаингибирования коррозию стали  СТ. 3 в воде.  Ноосфера, 2016, 16, 126-135.
  34. BULHAC, I.; DESEATNIC-CILOCI, A.;  CUBA,  L.; BIVOL, C.; DANILESCU, O.; DVORNINA, E.; BOUROŞ, P. Compuşicoordinativiaifierului(III) cu activitatebiologică.  Proceedings of International Conference „Modern Technologies in the Food Industry”, 20-22 october, 2016 Chişinău, pp. 348-355.
  35. COROPCEANU, E.; CILOCI, A.; ŞTEFÎRŢĂ, A.; BULHAC, I. Compuşicoordinativioximiciîncalitate de stimulatoriaiproceselorfiziologice la unii fungi şiplante de cultură.  Proceedings of International Conference „Modern Technologies in the Food Industry”, 20-22 october 2016, Chişinău, pp. 369-374.
  36. BULHAC, I.; CUBA, L.; SILION, M.; DRAGANCEA D.; BOUROSH, P. New iron(III) coordination compounds with 2,3-butanedione bis((iso)nicotinoylhydrazone). A XXXIV-a Conferinţănaţională de chimie, 04-07 octombrie 2016, Călimăneşti-Căciulata, judeţulVâlcea, România P.S.II, p. 2.
  37. CUBA,L.; BULHAC,I.; BOUROSH, P.. Synthesis and crystal structure of seven coordinated Fe(III) with tetradentatedihydrazone in [Fe(H2L)(H2O)3](NO3)3·2H2O.  The 8th International Conference on materials science and condensed matter physics, Chisinau, Moldova, September 12-16, 2016. Abstracts, p.173.
  38. ROTARU, M.; COCU, M.; SILION, M.; BULHAC, I.; KRAVTSOV, V.; BOUROSH, P. The vanadium(IV) binuclear coordination compound bazed on 1-phenyl-1,3-butanedione isonicotinoylhydrazone.  A XXXIV-a Conferinţănaţională de chimie, 04-07 octombrie 2016, Călimăneşti-Căciulata, judeţulVâlcea, România P.S.II, p. 1.
  39. ŞTEFÎRȚĂ, A.; BULHAC, I.; BOTNARI, V.; MELENCIUC, M.; BRÎNZĂ L.; LEAHU Ig.; BUCEACEAIA S.. Un noupreparat de optimizare a stăriifuncţionaleşiproductivităţiiplantelor.  Biotehnologiiavansate - Realizărişi perspective al IV-lea Simpozionnaţional cu participareinternaţională, 3-4 octombrie 2016, Chişinău, Republica Moldova, p. 118.
  40. БУЛХАК, И.; ДАНИЛЕСКУ, О.; РИЖА, А.; ШОВА, С.; КРАВЦОВ, В.Х.; БОУРОШ, П.Н. Синтезкристаллическая структура комплексов Со(П) с пентадентатнымиШиффовыми основаниями 2,6-диацетилпиридингидразонов. Координационнаяхимия, 2017, 43(1) 23-38 (rusă). ISSN 0132-344X. (IF:  0,541).
  41. b) BULHAC, I.; DANILESCU, O.; RIJA, A.; SHOVA, S.; KRAVTSOV, V.Ch.;    BOUROSH, P.N. Cobalt(II) Complexes with Pentadentate Schiff Bases 2,6-Diacetylpiridine Hydrazones: Syntheses and Structures.  Russian Journal of Coordination Chemistry. 2017, 43(1), p. 21-36. ISSN 1070-3284. (engleză) (IF: 0,541).
  42. БОУРОШ, П.; БОЛОГА, О.; ДЕСЯТНИК-ЧИЛОЧИ, А.; ТЮРИНА, Ж.; БУЛХАК, И. Синтезистроениесмешанныхдиоксиматовкобальта(Ш) спроизводнымигуанидинаиихбиологическиесвойства.  Координационнаяхимия. 2017, 43(9), c. 553-562. ISSN0132-344X. (rusă). (IF:  0,541).
  43. BOUROSH, P.; BOLOGA, O.; DESEATNIC-CILOCI, A.; TIURINA, J.; BULHAC, I. Synthesis, Structure, and Biological Properties of Mixed Cobalt(III) Dioximates with Guanidine Derivatives.  Russian Journal of Coordination Chemistry, 2017, 43(9), p. 591-599. ISSN 1070-3284. (engleză). (IF: 0,541).
  44. ȘTEFÎRȚĂ, A.; BOTNARI, V.; BRÂNZĂ, L.; BULHAC, I.; COROPCEANU, E.; BOUROSH, P.; CHILINCIUC, A. Possibilities of increasing the antioxidant properties of garlic plants (Allium Sativum, L.).  ActaChemicaIași. 2017, 25(2), 208-231. DOI: 10.1515/achi-2017-0017.ISSN 2067 - 2438.
  45. БОЛОГА, О.А.; ПAРШУТИН, В.В.; ШОЛТОЯН,  Н.С.; КОВАЛЬ, А.В.;   ЧЕРНЫШЕВА, Н.В.; ВЕРЕЖАН, А.В.; БУЛХАК, И.И. Ингибирование коррозии Ст.3 в воде комплесным соединением – хлористый дигидразидсемикарбазид диуксусной кислоты никеля(П) тригидрат.  Электронная обработка материалов, том. 53, № 6, 2017.
  46. BULHAC, Ion; STEFIRTSA, Anastasia; BOTNARI, Vasilii; COROPCEANU, Eduard; BRINZA, Lilia; MELENCIUC, Mihail; BOUROSH, Paulina. The  effect of some coordination compounds on physiological processes of plants under the environmental stress.  The 6th International Confernce ”Ecological & Environmental Chemistry-2017”, Abstracts book. March 2-3, 2017. Chisinau, Moldova. P. 152-153. ISBN: 978-9975-51-  810-9.
  47. DANILESCU, O.; BOUROSH, P.; BULHAC, I. Synthesis and structure of iron(III) coordination compounds with 2,6-diacetylpyridine bis((iso)nicotinoylhydrazones) and coordinated isothiocyanate ions.  27th International Chugaev Conference on Coodination Chemistry. Abstracts book. October 2-6, 2017. Nizhny Novgorod, Russia, p. 210.
  48. DANILESCU, O.; PETUHOV, O.; BULHAC, I.; BOUROSH P. Thermal study of Fe(III) complexes with 2,6-diacetylpyridine bis((iso)nicotinoylhydrazone).  4th Central and Eastern European Conference on Thermal Analysis and Calorimetry. Abstracts book. August 28-31, 2017. Chişinău, Moldova. PS3.17, p. 413.
  49. DANILESCU, Olga; BOUROȘ, Pavlina; BULHAC, Ion. Sintezașistudiulpolimerilor 2D aiZn(II) înbaza 2,6-diacetilpiridină bis((izo)nicotinoilhidrazone)-lor.  The 9th International Conference “Microelectronics and Computer Science” & The 6th Conference of Physicists of Moldova. Abstracts book. October 19-21, 2017. Chișinău, Moldova, p. 433.
  50. ROTARU, Mihaela; COCU, Maria; DRAGANCEA, Diana; BULHAC, Ion; BOUROSH, Polina. Synthesis and Crystal Structure of New Organic Ligand Based on S-ethylisolthiosemicarbazide.  The 6th International Conference “Ecological & Environmental Chemistry-2017”. Abstracts book. March 2-3, 2017. Chișinău, Moldova. p. 11. ISBN: 978-9975-51-810-9.
  51. ŞTEFÎRŢĂ, A.; BOTNARI, V.; BULHAC, I.;    BRÂNZĂ, L.;  CHILINCIUC, A.; COROPCEANU, E.; BOUROŞ, P. Procedeu de cultivare a usturoiului. Brevet de invenţie MD 1087. 2016-11-data. Data publicării  Z 2017.06.30.
  52. БОУРОШ, П.; БУЛХАК, И.; КОВАЧ, О.; ЗУБАРЕВА, В.; МИТИНА, Т. Бис-α-Бензилдиоксиматные комплексы железа(II) с 3- и 4-пиридин полуацеталями в качестве аксиальныхли гандов: синтез, строение и физико-химические свойства. Координационная химия, 2018, 44(4), 255-265 (FI: 0.717).
  53. BOUROSH, P.; BULHAC, I.; COVACI, O.; ZUBAREVA, V.; MITINA, T. Iron(II) Bis-α-Benzyldioximate Complexes with 3- and 4-Pyridine Hemiacetals as Axial Ligands: Synthesis, Structure, and Physicochemical Properties. Russian Journal of Coordination Chemistry, 2018, 44(8), pp. 507-517. ISSN 1070-3284.
  54. BULHAC, I.; DANILESCU, O. Sintezașidesignul molecular al complecșilorV(II,IV), FeIII, CoII, CuIIșiZnII cu 2,6-diacetilpiridină bis((izo)nicotinoilhidrazone).  A XXXV-a ConferinţăNaţională de Chimie,  02 - 05 octombrie 2018, Călimăneşti - Căciulata, judeţulVâlcea, România, p. 6.
  55. COCU, M.; CROITOR L.; BOUROSH, P.; TITICA, T.; DANILESCU, O.; BULHAC, I. Template synthesis and crystal structure of new triheteronuclear complex based on 2,6-diacetylpyridine and isonicotinic acid hydrazide.  The 9th International Conference on Material Science and Condenced Matter Physic., September 25-28, 2018, Chișinău, Moldova, p.116.
  56. COCU, M.; CROITOR L.; BOUROSH, P.; TITICA, T.; DANILESCU, O.; BULHAC, I. New mononuclear manganese(II) complex based on 2,6-diacetylpyridine bis(isonicotinoylhidrazone).  A XXXV-a Conferințănațională de chimie, 02-05 octombrie 2018, Călimănești-Căciulata, județulVâlcea, România, P.S.II, p. 6.
  57. DANILESCU, O.; BOUROSH, P.; BULHAC, I. Synthesis and structural study of Cu(II) binuclear complexes with 2,6-diacetylpyridine bis((iso)nicotinoylhydrazone).  The 9th International Conference on Materials Science and Condensed Matter Physics (MSCMP 2018), september 25-28, 2018, Chisinau, Moldova, p. 118.
  58. DANILESCU, O.; BULHAC, I.; BOUROȘ, P. Sintezașistructurapolimeruluicoordinativ 2D de cobalt(II) cu 2,6-diacetilpiridină bis(nicotinoilhidrazona).  A XXXV-a ConferințăNațională de Chimie, 02 - 05 octombrie 2018, Călimăneşti - Căciulata, judeţulVâlcea, România, p. 12.
  59. DANILESCU, O.; PETUHOV, O.; BULHAC, I.; BOUROSH, P. Thermal study of Zn(II) complexes with 2,6-diacetylpyridine bis((iso)nicotinoylhydrazone).  12th European Symposium on Thermal Analysis and Calorimetry (ESTAC12), 27-30 august 2018, Brasov, Romania, p. 535.
  60. URECHE, D. V.;  BULHAC, I. I.; RIJA, A. P.;  BOUROSH, P. N. New binuclear compounds of Zn(II) and Mn(II) based on dianilineglyoxime and isophthalic acid.  9th International Conference Materials Science and Condensed Matter Physics (MSCMP), 25-28 september 2018, Chișinău, Moldova. p. 138.
  61. URECHE, D.; BOUROSH, P.; RIJA, A.; BULHAC, I. Thermal analysis of new binuclear compounds of Zn(II) and Mn(II) based on dianilineglyoxime and isophthalic acid. 12th European Symposium on Thermal Analysis and Calorimetry (ESTAC12), 27 – 30 August 2018, Brasov, Romania. p. 539.
  62. BULHAC Ion; DESEATNIC-CILOCI Alexandra; CUBA Lidia; TIURINA Jana;  BOUROŞ Polina;  DRAGANCEA Diana;  CLAPCO Steliana. Azotaţi de (2,3-butandiona-bis-(izonicotinoilhidrazo-nă)-tris-acua)fier(III) monohidraţiîncalitate de stimulatoriai sin-tezeienzimelorproteolitice la cultivareatulpinii de fungi micelialiFusariumgibbosum CNMN FD 12. Brevet de invențienr. 4509 C1. Eliberat la 2018.03.31.
  63. PARȘUTIN, V.; ȘOLTOIAN, N.; CERNÎȘEVA, N.; COVALI, A.; COROPCEANU, E.; BULHAC, I. Inhibitor de coroziune a oțeluluiînapă. Brevet de invenție MD 1257 Y. Eliberat la 2018.05.31.
  64. КОРОПЧАНУ, Э.; РУДИК, В.; ЧЕПОЙ, Л.; РУДЬ, Л.; ЛОЗАН, В.; КИРИЯК, Т.; МИСКУ, В.; БУЛХАК, И.; КРАВЦОВ, В.; БОУРОШ, П. Синтезиструктура [Co(DmgH)2(Thio)2]2F[PF6]. Влияние фторсодержащихдиоксиматовCo(III) на физиологические процессы микроводоросли Porphyridiumcruentum. Коорд. Химия. 2019, 45(3), 170–177.ISSN (PRINT) 0132-344X(IF:0,674).
  65. COROPCEANU, E.; RUDIC, V.; CEPOI, L.; RUDI, L.; LOZAN, V.; CHIRIAC, T.; MISCU, V.; BULHAC, I.; KRAVTSOV, V.; BOUROSH, P. Synthesis and Crystal Structure of [Co(DmgH)2(Thio)2]2F[PF6]. The Effect of alga Porphyridiumcruentum. In: Russian Journal of Coordination Chemistry.2019, 45(3), 206–213. ISSN (PRINT) -3284(IF: 0,674).
  66. УРЕКЕ, Д.; БУЛХАК, И.; РИЖА, А.; КОРОПЧАНУ, Э.; БОУРОШ, П. Синтез и структура соли дианилинглиоксима и его биядерных комплексов Zn(II) и Mn(II) с 1,3-бензолдикарбоновой кислотой. Координационнаяхимия. 2019, 45(12), 720-733. ISSN (PRINT) 0132-344X(IF:0,674).
  67. URECHE, D.; BULHAC, I.; RIJA, A.; COROPCEANU E.; BOUROSH, P. Dianilineglyoxime Salt and Its Binuclear Zn(II) and Mn(II) Complexes with 1,3-Benzenedicarboxylic Acid: Synthesis and Structures. Russ. J. Coord. Chem. 2019, 45(12), 843-855. ISSN (PRINT) 1070-3284 (IF:0,674)


Abstracts

  1. BULHAC, I., DANILESCU, O. Compuși coordinativi ai unor metale tranziționale 3d cu baze Schiff heterociclice. Sinteză, structură, proprietăți. Învățământ superior: tradiții, valori, perspective” conferințaștiințificănațională cu participareinternaţională. 27-28 septembrie 2019, Chișinău, vol. I,  pp. 12-17.  ISBN 978-9975-76-284-7.
  2. DANILESCU, O.; COCU, M.; BULHAC, I.; BOUROSH, P. Polymeric Mn(II) coordination compounds based on bis((iso)nicotinoylhydrazones) N5O2 donor ligands. International Conference „Achievements and perspectives of modern chemistry”, dedicated to the 60-th anniversary from the foundation of the Institute of Chemistry. October 9-11, 2019, Chișinau, Republic of Moldova, Book of abstracts, P 26, pag. 92. ISBN 978-9975-62-428-2.
  3. DANILESCU, O.; COCU, M.; BULHAC, I.; PETUHOV, O.; BOUROSH, P. Sinteza, structura și proprietățile sorbționale ale polimerilor coordinative bi- și tri- dimensionali cu liganzi în baza 2,6-diacetilpiridinei. Zilele Academiei Ieșene. A XXVII-a Sesiune de Comunicări Științifice a Institutului de Chimie Macromoleculară ”Petru Poni”, Iași. 2-4 octombrie 2019, Book of abstracts, Co 27, p. 59. (comunicare orală)
  4. URECHE, Dumitru; BULHAC, Ion; KRAVTSOV, Viktor; BOUROSH, Paulina. A novel copper(II) 2D coordination polymer constructed of iminodiacetic acid. International Conference ”Achievements and perspectives of modern chemistry” dedicated to the 60th anniversary from the foundation of the Institute of Chemistry.9-11 octombrie 2019, Chişinău, RepublicofMoldova, 2019, p. 150.
  5. VERLAN, V.; CULEAC, I. P.; BORDIAN, O., ZUBAREVA, V. E.; BULHAC, I.; IOVU, M. S.; ENACHESCU, M.; SIMINEL, N. A.; NEDELEA, V. V. Luminescence Properties of a Novel Eu3+ Dinuclear Coordination Compound. Proceedings of. 4th International Conference on Nanotechnologies and Biomedical Engineering ( ICNB ME-2019), September 18 – 21, 2019, p.161 – 165. Editors: Ion Tiginyanu Victor Sontea, SergheiRailean, Chisinau, Moldova,  ISSN 1680-0737 ISSN 1433-9277 (electronic)IFMBE Proceedings ISBN 978-3-030-31865-9 ISBN 978-3-030-31866-6 (eBook) https://doi.org/10.1007/978-3-030-31866-6 Springer Nature Switzerland AG 2020IFMBE Proceedings,  Volume 77.
  6. VERLAN, V.; CULEAC, I. P.; BORDIAN, O., ZUBAREVA, V. E.; BULHAC, I.; IOVU, M. S.; ENACHESCU, M.; SIMINEL, N. A.; NEDELEA, V. V. Luminescence properties of a novel Eu3+ dinuclear coordination compound. 4th International Conference on Nanotechnologies and Biomedical Engineering ICNBME-2019, September 18-21, 2019, Chisinau, Republic of Moldova. Book of abstract, p. 83.
  7. ZUBAREVA, Vera;BOUROSH, Paulina; , BULHAC Ion.  Synthesis and crystal structures of ammonium salts of cobalt(III) and cobalt(II) based on dipicolinic acid. International Conference ”Achievements and perspectives of modern chemistry” dedicated to the 60th anniversary from the foundation of the Institute of Chemistry. October, 9-11 2019, Chisinau, Republic of Moldova, Book of abstracts, P86, p. 52. ISBN 978-9975-62-428-2.
  8. CILOCI, A., TIURINA, J., BULHAC, I., DANILESCU,O., LABLIUC, S., DVORNINA, E. Mediunutritivpentrucultivareatulpinii de fungi Fusariumgibbosum CNMN FD 12. Brevet de invenție.MD 4645 B1. 2019.08.31
  9. PARŞUTIN Vladimir; ŞOLTOIAN Nicolae; CERNÎŞEVA Natalia; COVALI Alexandr; COROPCEANU Eduard; BULHAC Ion. Inhibitor de coroziune a oţeluluiînapă. Brevet de invenţie de scurtădurată MD 1257. 2019-01-31.
  10. ȘTEFÎRȘĂ, A.; BRÎNZĂ L.; BULHAC, Ion; COROPCEANU, E.; BUCEACEAIA, S.; IONAȘCU, A.; COVACI, O. Procedeu de cultivare a plantelor de cultură. Brevet de invenție MD 1348 Y 2019. 07.31.
  11. URECHE, Dumitru;BULHAK, Ion; BOUROSH, Pavlina. A novel cooper(II) 2D coordination polymer and its thermal decompositio. In: Central and Eastern European Conference on Thermal Analysis and Calorimetryand 14th Mediterranean Conference on Calorimetry and Thermal Analysis. Editia 5, 28-31 august 2017, Chişinău. Roma, Italy: Academica Greifswald, 2019, p. 312. ISBN 978-3-940237-59-0.
  12. URECHE, Dumitru; BULHAK, Ion; KRAVTSOV, Victor; BOUROSH, Pavlina. A novel copper(II) 2D coordination polymer constructed of iminodiacetic acid. In: Achievements and perspectives of modern chemistry. 9-11 octombrie 2019, Chişinău. Chisinau, Republic of Moldova: Tipografia Academiei de Ştiinţe a Moldovei, 2019, p. 150. ISBN 978-9975-62-428-2.
  13. URECHE, Dumitru; BULHAK, Ion; RIJA, Andrei; COROPCEANU, Eduard; BOUROSH, Pavlina. Dianilineglyoxime Salt and Its Binuclear Zn(II) and Mn(II) Complexes with 1,3-Benzenedicarboxylic Acid: Synthesis and Structures. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019, nr. 12(45), pp. 843-855. ISSN.
  14. URECHE, Dumitru; BULHAK, Ion; RIJA, Andrei; BOUROSH, Pavlina. New binuclear compounds of Zn(II) and Mn(II) based on dianilineglyoxime and isophthalic acid. In: Materials Science and Condensed Matter Physics. Ediția a 9-a, 25-28 septembrie 2018, Chișinău. Chișinău, Republica Moldova: Institutul de Fizică Aplicată, 2018, p. 138.


Patents

  1. BULHAC, I.; ȘTEFÎRȚĂ, A.; COROPCEANU, E.; BRÂNZĂ, L.; COVACI, O. Preparat complex cu proprietățiantioxidante. Patent MD 4647 C1 2020.04.30.
  2. ȘTEFÎRȚĂ, A.; BRÎNZĂ, L.; BULHAC, I.; COROPCEANU, E.; BUCEACEAIA, S.; IONAȘCU, A.; COVACI, O. Procedeu de cultivare a plantelor de cultură. Patent MD 1348 Z 2020.02.29.
  3. DANILESCU, O.; BOUROȘ, P.; PETUHOV, O.; BULHAC, I.; ȘOVA, S. Polimer coordinative 2,6-diacetilpiridinbis(izonicotinoilhidrazonato)(2-)cobalt(II)-apă(1/5,75) care manifestăproprietățiadsorbtive. Patent MD 4672 B1 2020.01.31.
  4. ZUBAREVA, V.; BULHAC, I.; BORDIAN, O.; VERLAN, V.; CULEAC, I.; ENACHESCU, M. RO; MOISE, C.C.RO. Compus coordinative dinuclear al europiului(III) cu liganzimicști, care manifestăproprietățiluminescente. Patent MD B1 2020.02.29.

Naional projects

  1. Synthesis and study of new materials based on coordination compounds with polyfunctional ligands and with useful properties in medicine, biology and technology (code 010602)
    Period: 2024-2027
    Subprogram manager: Dr. habilitate, assoc. prof. Vasile LOZAN
  2. ANCD/20.80009.5007.28. Elaboration of new multifunctional materials and efficient technologies for agriculture, medicine, technics and educational system based on the "s" and "d" metals complexes with polydentate ligands.
    Period: 2020-2023
    Project manager: Dr. habilitate, assoc. prof. Ion BULHAC
  3. CSSDT/15.817.02.18A. Assembly and study of transition metal complexes based on polyfunctional and macrocyclic ligands useful for agriculture, food industry and advanced biotechnologies
    Period: 2015-2019
    Project manager: Dr. habilitate, assoc. prof. Ion BULHAC
  4. CSȘDT/16.00353.50.03A. Molecular and supramolecular architectures of lanthanides for magnetic applications
    Period: 2016-2017
    Project manager: Dr., assoc. prof. Diana DRAGANCEA